This paper introduced supersonic expansion liquefaction technology into the field of hydrogen liquefaction. The mathematical model for supersonic condensation of hydrogen gas in a Laval nozzle model was established. The supersonic expansion and condensation characteristics of hydrogen gas under different temperature conditions were investigated. The simulation results show that the droplet number rises rapidly from 0 at the nozzle throat as the inlet temperature increases

and the maximum droplet number generated is 1.339×10

18

kg

-1

at inlet temperature of 36.0 K. When hydrogen nucleation occurs

the droplet radius increases significantly and shows a positive correlation with the increase in the inlet temperature

and the maximum droplet radii are 6.667×10

-8

m

1.043×10

-7

m

and 1.099×10

-7

m when the inlet temperature is 36.0 K

36.5 K

and 37.0 K

respectively. The maximum nucleation rate decreases with increasing inlet temperature

and the nucleation region of the Laval nozzle becomes wider. The liquefaction efficiency can be effectively improved by lowering the inlet temperature. This is because a lower inlet temperature provides more subcooling

which allows the hydrogen to reach the thermodynamic conditions required for large-scale condensation more quickly.