Production of linear alkylbenzene over Ce containing Beta zeolites
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Production of linear alkylbenzene over Ce containing Beta zeolites
Production of linear alkylbenzene over Ce containing Beta zeolites
中国化学工程学报(英文版)2024年67卷第3期 页码:220-227
Affiliations:
1. School of Chemical Engineering and Light Industry, Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology,Guangzhou,China,510006
2. Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory),Jieyang,China,515200
Shiqi Zhang, Shengzhi Gan, Baoyu Liu, 等. Production of linear alkylbenzene over Ce containing Beta zeolites[J]. 中国化学工程学报(英文版), 2024,67(3):220-227.
Shiqi Zhang, Shengzhi Gan, Baoyu Liu, Jinxiang Dong. Production of linear alkylbenzene over Ce containing Beta zeolites[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 220-227.
Shiqi Zhang, Shengzhi Gan, Baoyu Liu, 等. Production of linear alkylbenzene over Ce containing Beta zeolites[J]. 中国化学工程学报(英文版), 2024,67(3):220-227.DOI: 10.1016/j.cjche.2023.11.007.
Shiqi Zhang, Shengzhi Gan, Baoyu Liu, Jinxiang Dong. Production of linear alkylbenzene over Ce containing Beta zeolites[J]. Chinese Journal of Chemical Engineering, 2024, 67(3): 220-227.DOI: 10.1016/j.cjche.2023.11.007.
Production of linear alkylbenzene over Ce containing Beta zeolites
Ce-encapsulated Beta zeolite was synthesized by a one-pot hydrothermal method with citric acid complexing Ce in the absence of Na species. Additional citric acid can effectively prevent the deposition of Ce species during the hydrothermal synthesis of zeolites
leading to uniform distribution of Ce cluster in the framework of Beta zeolites. Moreover
the sodium-free synthesis system resulted that the Brønsted acid sites were mainly located on the straight channels and external surface of Beta zeolites
improving the utilization of Brønsted acid sites. In addition
Ce encapsulated Beta zeolites showed enhanced activity and robust stability in the alkylation of benzene with 1-dodecene based on the synergistic effect between Ce species and Brønsted acid sites
which pave the way for its practical application in the production of alkylbenzene.
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相关作者
Lu Junning
Cai Xuming
Zhang Huali
Huang Yi
Liu Baoyu
Ting Pu
Junning Lu
Zhirui Liu
相关机构
School of Chemical Engineering and Light Industry, Guangdong University of Technology
School of Engineering, Institute for Materials & Processes, The University of Edinburgh, Edinburgh EH93FB, United Kingdom
Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center
School of Engineering, Institute for Materials & Processes, The University of Edinburgh, Robert Stevenson Road, Edinburgh EH9 3FB, United Kingdom
Department of Chemistry, Xinzhou Normal University