High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study
Chemical Engineering Thermodynamics|Updated:2026-01-06
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High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study
High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study
中国化学工程学报(英文版)2021年32卷第4期 页码:281-290
Affiliations:
1. Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam,Selangor,Malaysia,40450
2. Department of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad,Iraq
3. Department of Chemistry, University of Saskatchewan,, Saskatchewan Canada,Saskatoon,S7N 5C9
4. Faculty of Chemical Engineering, Universiti Teknologi MARA, Shah Alam,Selangor,Malaysia,40450
5. Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
Ali H. Jawad, Ahmed Saud Abdulhameed, Lee D. Wilson, 等. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study[J]. 中国化学工程学报(英文版), 2021,32(4):281-290.
Ali H. Jawad, Ahmed Saud Abdulhameed, Lee D. Wilson, Syed Shatir A. Syed-Hassan, Zeid A. ALOthman, Mohammad Rizwan Khan. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 281-290.
Ali H. Jawad, Ahmed Saud Abdulhameed, Lee D. Wilson, 等. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study[J]. 中国化学工程学报(英文版), 2021,32(4):281-290.DOI: 10.1016/j.cjche.2020.09.070.
Ali H. Jawad, Ahmed Saud Abdulhameed, Lee D. Wilson, Syed Shatir A. Syed-Hassan, Zeid A. ALOthman, Mohammad Rizwan Khan. High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 281-290.DOI: 10.1016/j.cjche.2020.09.070.
High surface area and mesoporous activated carbon from KOH-activated dragon fruit peels for methylene blue dye adsorption: Optimization and mechanism study
摘要
Abstract
In this study
an alternative precursor for production of activated carbon was introduced using dragon fruit (
Hylocereus costaricensis
) peel (DFP). Moreover
KOH was used as a chemical activator in the thermal carbonization process to convert DFP into activated carbon (DFPAC). In order to accomplish this research
several approaches were employed to examine the elemental composition
surface properties
amorphous and crystalline nature
essential active group
and surface morphology of the DFPAC. The Brunauer-Emmett-Teller test demonstrated a mesoporous structure of the DFPAC has a high surface area of 756.3 m
2
·g
-1
. The cationic dye Methylene Blue (MB) was used as a probe to assess the efficiency of DFPAC towards the removal of MB dye from aqueous solution. The effects of adsorption input factors (
e.g
. DFPAC dose (A:0.04-0.12 g·g
-1
)
pH (B:3-10)
and temperature (C:30-50℃)) were investigated and optimized using statistical analysis (
i.e
. Box-Behnken design (BBD)). The adsorption kinetic model can be best categorized as the pseudo-first order (PFO). Whereas
the adsorption isother
m model can be best described by Langmuir model
with maximum adsorption capacity of DFPAC for MB dye was 195.2 mg·g
-1
at 50℃. The adsorption mechanism of MB by DFPAC surface was attributed to the electrostatic interaction
p-p interaction
and H-bonding. Finally
the results support the ability of DFP to be a promising precursor for production of highly porous activated carbon suitable for removal of cationic dyes (
e.g
. MB).
关键词
Keywords
references
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相关作者
Jingru Dou
Yingxuan Wen
Fangfang Zhang
Falong Shan
Shougui Wang
Jipeng Dong
Fei Gao
Guanghui Chen
相关机构
College of Chemical Engineering, Qingdao University of Science and Technology
Department of Environmental Science and Engineering, Hubei Biomass-Resource Chemistry and Environmental Biotechnology Key Laboratory, School of Resource and Environmental Sciences, Wuhan University
Department of Environmental Science and Engineering, Anhui Science and Technology University, Fengyang
State Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology