Research on thermal risk and decomposition behavior of methyl nitrite

Haoyu Zhai; Shaomeng Wang; Diankun Chen; Xuanying Cheng; Chuanxin Xie

doi:10.1016/j.cjche.2020.05.031

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Research on thermal risk and decomposition behavior of methyl nitrite

Process Systems Engineering and Process Safety | Updated：2026-01-06

- Research on thermal risk and decomposition behavior of methyl nitrite
- Research on thermal risk and decomposition behavior of methyl nitrite
- 中国化学工程学报（英文版） 2020年28卷第8期页码：2131-2136
- Affiliations：
  
  College of Environment and Safety Engineering, Qingdao University of Science and Technology,Qingdao,China,266042
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2020.05.031
  中图分类号：
- 纸质出版：2020
- Accepted：
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Haoyu Zhai, Shaomeng Wang, Diankun Chen, 等. Research on thermal risk and decomposition behavior of methyl nitrite[J]. 中国化学工程学报（英文版）, 2020,28(8):2131-2136.

Haoyu Zhai, Shaomeng Wang, Diankun Chen, Xuanying Cheng, Chuanxin Xie. Research on thermal risk and decomposition behavior of methyl nitrite[J]. Chinese Journal of Chemical Engineering, 2020, 28(8): 2131-2136.
Haoyu Zhai, Shaomeng Wang, Diankun Chen, 等. Research on thermal risk and decomposition behavior of methyl nitrite[J]. 中国化学工程学报（英文版）, 2020,28(8):2131-2136. DOI： 10.1016/j.cjche.2020.05.031.

Haoyu Zhai, Shaomeng Wang, Diankun Chen, Xuanying Cheng, Chuanxin Xie. Research on thermal risk and decomposition behavior of methyl nitrite[J]. Chinese Journal of Chemical Engineering, 2020, 28(8): 2131-2136. DOI： 10.1016/j.cjche.2020.05.031.

摘要

Abstract

The thermal hazards of methyl nitrite (MN) were investigated in the present study. The determination and evaluation of MN decomposition were conducted using a C600 micro thermometer. The thermal runaway reaction characteristics of the compound under different initial pressures were obtained using a VSP2 calorimeter. The kinetic parameters of MN were obtained by regression fitting and calculation of the microthermal experimental data. The experimental and calculated results demonstrated that the potential explosion risk of MN is very high. In addition

there was a high energy barrier in the early stage of the uncontrolled decomposition of MN; however

once the decomposition reaction was initiated

the subsequent decomposition was easily conducted. Under the conditions of adiabatic simulation

the possibility that the reaction was uncontrolled increases with the initial temperature and pressure of the system

and there is a great potential safety risk.

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