Zhenhao Li, Bo Xing, Yan Ding, 等. A high-performance biochar produced from bamboo pyrolysis with in-situ nitrogen doping and activation for adsorption of phenol and methylene blue[J]. 中国化学工程学报(英文版), 2020,28(11):2872-2880. DOI: 10.1016/j.cjche.2020.03.031.
nitrogen doping and activation for adsorption of phenol and methylene blue[J]. 中国化学工程学报, 2020, 28(11): 2872-2880.
Zhenhao Li, Bo Xing, Yan Ding, 等. A high-performance biochar produced from bamboo pyrolysis with in-situ nitrogen doping and activation for adsorption of phenol and methylene blue[J]. 中国化学工程学报(英文版), 2020,28(11):2872-2880. DOI: 10.1016/j.cjche.2020.03.031.DOI:
nitrogen doping and activation for adsorption of phenol and methylene blue[J]. 中国化学工程学报, 2020, 28(11): 2872-2880.DOI: 10.1016/j.cjche.2020.03.031.
A high-performance biochar produced from bamboo pyrolysis with in-situ nitrogen doping and activation for adsorption of phenol and methylene blue
Nitrogen doping is a promising method for the preparation of functional carbon materials. In this study
a nitrogen-doped porous coral biochar was prepared by using bamboo as raw material
urea as nitrogen source
and KHCO
3
as green activator through
in-situ
pyrolysis. The structure of the obtained biochar was characterized by various techniques including nitrogen adsorption and desorption
Raman spectroscopy
X-ray photoelectron spectrometer
and
etc
. The adsorption properties of nitrogen-doped biochar were evaluated with phenol and methylene blue probes. The results showed that the nitrogen source ratio had a significant effect on the evolution of pore structure of biochar. Low urea addition ratio was beneficial to the development of pore structures. The optimum specific surface area of nitrogen-doped biochar could be up to 1693 m
2
·g
-1
. Nitrogen doping can effectively improve the adsorption capacity of biochar to phenol and methylene blue. Biochar prepared at 973.15 K with low urea addition ratio exhibited the highest adsorption capacity for phenol and methylene blu
e
and the equilibrium adsorption capacity was 169.0 mg·g
-1
and 499.3 mg·g
-1
respectively. By comparing the adsorption capacity of various adsorbents in related fields
it is proved that the nitrogen-doped biochar prepared in this study has a good adsorption effect.
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