Atefeh Moosavi, Ali Akbar Amooey, Ali Alinejad mir, 等. Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell[J]. 中国化学工程学报(英文版), 2020,(6):1591-1602.
Atefeh Moosavi, Ali Akbar Amooey, Ali Alinejad mir, et al. Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell[J]. Chinese Journal of Chemical Engineering, 2020, (6): 1591-1602.
Atefeh Moosavi, Ali Akbar Amooey, Ali Alinejad mir, 等. Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell[J]. 中国化学工程学报(英文版), 2020,(6):1591-1602.DOI: 10.1016/j.cjche.2020.02.031.
Atefeh Moosavi, Ali Akbar Amooey, Ali Alinejad mir, et al. Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell[J]. Chinese Journal of Chemical Engineering, 2020, (6): 1591-1602.DOI: 10.1016/j.cjche.2020.02.031.
Extraordinary adsorption of acidic fuchsine and malachite green onto cheap nano-adsorbent derived from eggshell
Removal of dyestuffs such as Acidic Fuchsine (AF) and Malachite Green (MG) being present in many forms in industries is vital to protect water reservoirs from their catastrophic effects on the ecosystem. This study attempts to effectively eliminate these dyes using a low-cost and eco-friendly material. Eggshell
as a biocompatible by-product
was initially characterized
then some modifications were conducted
and its morphology and chemical structure were then examined through (Atomic force microscopy) AFM
(Fourier-Transform Infrared Spectroscopy) FTIR
(Energy-Dispersive X-ray Spectroscopy) EDS and (Brunauer-Emmett-Teller) BET analyses. They revealed that the modifications on raw material gave rise to a natural nano-adsorbent presenting porous medium appropriate for targeted adsorbate molecules with the average particle size and average pore diameter of 54 and ~2 nm
respectively. Functional groups on the adsorbent surface were also of importance to assist the adsorption of AF and MG. The effect of contact time
adsorbent dose
solution pH and initial concentration was evaluated. Pseudo-second order model accurately correlated the experimental kinetic data for both dyes. Mor
eover
the participation of intra-particle diffusion along with film diffusion in controlling the process was suggested. Langmuir isotherm model fitted very well to the equilibrium data for both dyes and maximum monolayer adsorption capacity of AF and MG was accordingly calculated to be 5000 and 3333.33mg·g
-1
respectively. The inherent characteristics of eggshell make it a potential material to remove contaminants from wastewater in future applications.
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相关作者
Aishun Ma
Hanlin Qian
Hongxia Liu
Sili Ren
Yawei Shi
Guozhu Liu
Mingde Li
Liang Wang
相关机构
Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology
Jiangxi Provincial Key Laboratory of Low-Carbon Processing and Utilization of Strategic Metal Mineral Resources, Jiangxi University of Science and Technology
State Key Laboratory of Separation Membranes and Membrane Processes, School of Environmental Science and Engineering, Tianjin Polytechnic University
School of Chemical Engineering and Technology, Tianjin University
Hangzhou Environmental Protection Research Institute of China Coal Technology & Engineering Group