Rui Shan, Yueyue Shi, Jing Gu, 等. Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems[J]. 中国化学工程学报(英文版), 2020,28(5):1375-1383.
Rui Shan, Yueyue Shi, Jing Gu, Yazhuo Wang, Haoran Yuan. Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1375-1383.
Rui Shan, Yueyue Shi, Jing Gu, 等. Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems[J]. 中国化学工程学报(英文版), 2020,28(5):1375-1383.DOI: 10.1016/j.cjche.2020.02.012.
Rui Shan, Yueyue Shi, Jing Gu, Yazhuo Wang, Haoran Yuan. Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1375-1383.DOI: 10.1016/j.cjche.2020.02.012.
Single and competitive adsorption affinity of heavy metals toward peanut shell-derived biochar and its mechanisms in aqueous systems
摘要
Abstract
Converting peanut shells into biochar by pyrolysis was considered an environmentally friendly and efficient method for agricultural solid waste disposal. The properties of peanut shell-derived biochar (PBC) under different temperature and its adsorption capacity of heavy metals were investigated. It was found that PBC400 exhibited the highest cumulative capability for heavy metals elimination in single solute because of its high specific surface area and rich functional groups. Furthermore
the competitive adsorption revealed that PBC had a substantial difference in adsorption affinity from diverse heavy metal ions
sorption capacity decreased as Pb
2+
Cu
2+
Cd
2+
Ni
2+
Zn
2+
which was lower than in a single solute. The adsorption process using selected biochar was optimized with respect to pH
reaction time
adsorbent dose
and initial concentration of heavy metals. The kinetic data was well fitted with PSO model
and the Langmuir model was adopted for adsorption equilibrium data in both cases of single solutes and mixed solutes for all heavy metals
which indicated that the removal
course was primarily explained by monolayer adsorption
and chemical adsorption occupied an important role. Therefore
peanut shells derived biochar could be a potential and green adsorbent for wastewater treatment.
关键词
Keywords
references
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相关作者
Suchith Chellappan
Vaishakh Nair
Sajith V.
Aparna K.
Qiang Luyao
Bai Boyang
Sun Ming
Song Dengmeng
相关机构
2 Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw
3 School of Nano Science and Technology, National Institute of Technology, Calicut
College of Chemistry and Chemical Engineering, Xi'an Shiyou University
Shaanxi Engineering Research Center of Green Low-carbon Energy Materials and Processes, Xi'an Shiyou University
College of Chemistry and Materials Science, Weinan Normal University