Jinghang Li, Huimin Zang, Shun Yao, 等. Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide[J]. 中国化学工程学报(英文版), 2020,28(5):1397-1404.
Jinghang Li, Huimin Zang, Shun Yao, Zicheng Li, Hang Song. Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1397-1404.
Jinghang Li, Huimin Zang, Shun Yao, 等. Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide[J]. 中国化学工程学报(英文版), 2020,28(5):1397-1404.DOI: 10.1016/j.cjche.2020.02.006.
Jinghang Li, Huimin Zang, Shun Yao, Zicheng Li, Hang Song. Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1397-1404.DOI: 10.1016/j.cjche.2020.02.006.
Photodegradation of benzothiazole ionic liquids catalyzed by titanium dioxide and silver-loaded titanium dioxide
ionic liquids (ILs) have been widely used in extraction
synthesis
electrochemistry and other fields. Meanwhile
the environmental impact of ILs has been attracting a lot of attention
and eco-friendly treatment for ILs is becoming a necessary subject. In this study
photocatalytic degradations of benzothiazole ILs catalyzed by titanium dioxide (TiO
2
) and silver-loaded titanium dioxide (Ag/TiO
2
) were studied for the first time. The degradation of benzothiazole hexafluorophosphate ([C
4
Bth
]
PF
6
) could reach more than 99% within 240 min with the catalysis of TiO
2
. To improve catalytic efficiency
Ag/TiO
2
was synthesized and characterized by UV-Vis diffuse reflectance absorption spectra (DRS) and X-ray photoelectron spectroscopy (XPS). The degradation of[C
4
Bth
]
PF
6
could reach more than 99% within 120 min in the degradation catalyzed by Ag/TiO
2
. The photodegradation products of benzothiazole ILs are composed of inorganic substances or organic substances with simpler structures
which are easier to decompose and less toxic. The degradation syste
m proposed by this study could provide a simple
green
safe
and economical method for the efficient treatment of benzothiazole ILs.
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相关作者
Jue Li
Li Wang
Chunqiu Han
Fengyun Su
Yumin Leng
Liqun Ye
Qiu Xutao
Zhao Feng
相关机构
College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University
Engineering Technology Research Center of Henan Province for Solar Catalysis, College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University
College of Physics and Electronic Engineering, Nanyang Normal University
Beijing Laboratory of New Energy Storage Technology, Institute of Energy Power Innovation, North China Electric Power University