Adriana Reyes-Serrano, Joel E. López-Alejo, Manuel A. Hernández-Cortázar, 等. Removing contaminants from tannery wastewater by chemical precipitation using CaO and Ca(OH)2[J]. 中国化学工程学报(英文版), 2020,28(4):1107-1111. DOI: 10.1016/j.cjche.2019.12.023.
[J]. 中国化学工程学报, 2020, 28(4): 1107-1111.
Adriana Reyes-Serrano, Joel E. López-Alejo, Manuel A. Hernández-Cortázar, 等. Removing contaminants from tannery wastewater by chemical precipitation using CaO and Ca(OH)2[J]. 中国化学工程学报(英文版), 2020,28(4):1107-1111. DOI: 10.1016/j.cjche.2019.12.023.DOI:
sulfates and Chemical Oxygen Demand (COD) from industrial tannery wastewater by chemical precipitation was carried out using Calcium oxide (CaO) and Calcium hydroxide (Ca(OH)
2
). Different doses of alkalis
ranging from deficiency to excess hydroxyl species over the stoichiometric necessary
were used to remove theoretically the 100% of Cr [0.3-3.2 g alkali·(g Cr
3+
)
-1
]
. The precipitation was carried out at room temperature
10 min of vigorous stirring
200 r·min
-1
and a settling time of 24 h
followed by separation and characterization of liquid product. As result of addition of alkalis
pH underwent increase as did the alkali concentration. The removal of Cr
and sulfates also increased as alkali concentration did
although for first species the changes at higher alkali contents were less evident. COD removal on the other hand
did not follow a unique trend
instead exhibited a maximum. Based on our results
selection of a specific dose of alkali was carried out taking as reference the efficiency on total chromium removal
keeping the pH in the range 7 to 9 to ensure Cr precipitation as chromium hyd
roxide. With those conditions
jar test was used to produce enough liquid product in order to determine the removal percent of several other species. The removal percent of the species was as follows: Cr
SO
4
2-
ZnSO
4
FeSO
4
CN
-1
NiSO
4
Fe
2
[Fe(CN)
6
]
at 99.8%
66.9%
99.6%
21.4%
70.9%
52.8% and 76.4% with CaO
and 99.8%
61.6%
99.9%
7.1%
84.0%
54.4% and 90.5% with Ca(OH)
2
respectively.
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