/C composite was firstly synthesized by carbothermal reduction of silica-carbon binary xerogel. The homogeneous dispersion feature of the two components in binary xerogel contributes to effectively carbothermally reduce the O/Si atomic ratio
enhancing the electrochemical activity of the SiO
x
component. The micron-sized SiO x/C spheres are composed of many near-spherical nanoparticles. The synthesized SiO
x
/C exhibits a stable and high reversible capacity of 830 mA·h·g
-1
for 100 cycles
and excellent rate-capability. The homogeneous dispersion structure of phases
the micro/nanostructure and the high electrochemical activity of SiO
x
component combinedly contribute the excellent electrochemical performance.
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