Santiago Gutiérrez Ruiz, Juan Antonio López-Ramírez, Mohammed Hassani Zerrouk, 等. Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination[J]. 中国化学工程学报(英文版), 2020,28(3):733-742.
Santiago Gutiérrez Ruiz, Juan Antonio López-Ramírez, Mohammed Hassani Zerrouk, Agata Egea-Corbacho Lopera, José María Quiroga Alonso. Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination[J]. Chinese Journal of Chemical Engineering, 2020, 28(3): 733-742.
Santiago Gutiérrez Ruiz, Juan Antonio López-Ramírez, Mohammed Hassani Zerrouk, 等. Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination[J]. 中国化学工程学报(英文版), 2020,28(3):733-742.DOI: 10.1016/j.cjche.2019.10.004.
Santiago Gutiérrez Ruiz, Juan Antonio López-Ramírez, Mohammed Hassani Zerrouk, Agata Egea-Corbacho Lopera, José María Quiroga Alonso. Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination[J]. Chinese Journal of Chemical Engineering, 2020, 28(3): 733-742.DOI: 10.1016/j.cjche.2019.10.004.
Study of reverse osmosis membranes fouling by inorganic salts and colloidal particles during seawater desalination
Fouling phenomenon is considered among the major reasons that cause significant increase of operating cost of desalination plants equipped with reverse osmosis (RO) membranes. This phenomenon is studied in the present work in the case of RO polyamide aromatic membranes using model seawater containing inorganic salts and colloidal compounds. Different solubility conditions of CaCO
3
and CaSO
4
were applied to study RO performances with and without colloid presence. During experiments
the membrane permeate fluxes were continuously monitored. Moreover
studies of chemical composition
structure
and morphology of the materials deposited on the membrane surface were conducted using energy dispersive microanalysis (EDS) X-ray diffraction and scanning electronic microscopy (SEM). Results show that in conditions of calcium carbonate oversaturation there is a reduction in the permeate flow of 11.2% due to fouling of the membrane by the precipitation of this compound. While in the same conditions of calcium sulphate oversaturation the reduction of the flow is 5%
so we can conclude that in conditions of oversaturation of both salts
calcium carbonate produces a g
reater fouling of the membrane that in its view causes greater decrease in the flow of permeate. All this based on the results of the test with both salts in oversaturated conditions. Resulting in the formation of calcite and gypsum crystals onto the membranes as XRD analyses stated. Additional presence of colloidal silica in those conditions intensifies strongly the fouling
leading until to 24.1% of permeate flux decrease.
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references
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Model for seawater fouling and effects of temperature, flow velocity and surface free energy on seawater fouling
Research on composite scale inhibitors for inhibiting calcium carbonate scaling in high temperature geothermal fluid
Nanofiltration membranes embedded with thermo-responsive nanocapsules for crude glycerol desalination
Mechanistic insights into water desalination through two-dimensional MXene-graphene oxide membranes: A molecular simulation study
Copper hexacyanoferrate framework with dual redox centers for selective lithium extraction in hybrid capacitive deionization
相关作者
Dazhang Yang
Jianhua Liu
Xiaoxue E
Linlin Jiang
Li Shuai
Ma Yongli
Cao Baixu
Liu Mingyan
相关机构
2 Shanghai Key Laboratory of Multi-phase Flow and Heat Transfer
State Key Laboratory of Chemical Engineering and Low Carbon Technology (Tianjin University)
School of Chemical Engineering and Technology, Tianjin University
State Key Laboratory of Advanced Separation Membrane Materials, Zhejiang Province Key Laboratory of Biofuel, Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, and College of Chemical Engineering, Zhejiang University of Technology
Hubei Key Laboratory for Novel Reactor and Green Chemistry Technology, WIT-Qianjiang Research Institute of Green Chemical Industry, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology