Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes

Fatemeh Jafari; Navid Nasirizadeh; Mohammad Mirjalili

doi:10.1016/j.cjche.2019.05.001

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Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes

Materials and Product Engineering | Updated：2026-01-06

- Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes
- Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes
- 中国化学工程学报（英文版） 2020年28卷第1期页码：318-327
- Affiliations：
  
  Department of Textile and Polymer Engineering, Yazd Branch, Islamic Azad University, Yazd,Iran
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2019.05.001
  中图分类号：
- 纸质出版：2020
- Accepted：
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Fatemeh Jafari, Navid Nasirizadeh, Mohammad Mirjalili. Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes[J]. 中国化学工程学报（英文版）, 2020,28(1):318-327.

Fatemeh Jafari, Navid Nasirizadeh, Mohammad Mirjalili. Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes[J]. Chinese Journal of Chemical Engineering, 2020, 28(1): 318-327.
Fatemeh Jafari, Navid Nasirizadeh, Mohammad Mirjalili. Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes[J]. 中国化学工程学报（英文版）, 2020,28(1):318-327. DOI： 10.1016/j.cjche.2019.05.001.

Fatemeh Jafari, Navid Nasirizadeh, Mohammad Mirjalili. Enhanced degradation of reactive dyes using a novel carbon ceramic electrode based on copper nanoparticles and multiwall carbon nanotubes[J]. Chinese Journal of Chemical Engineering, 2020, 28(1): 318-327. DOI： 10.1016/j.cjche.2019.05.001.

摘要

Abstract

A novel carbon ceramic electrode consisting of CuNPs and MWCNT was developed to treat reactive orange 84 (RO84) wastewater using ultrasound-assisted electrochemical degradation. The proposed electrode generated more hydroxyl radicals than non-nanoparticle electrodes did. In addition

a new electrochemical sensor was applied to determine residue RO84 in an aqueous medium during discoloration. This sensor is based on a glassy carbon electrode modified with gold nanourchins and graphene oxide and can detect RO84 concentration in the range of 1.0-1200 μmol·L

-1

with the detection limit of 0.03 μmol·L

-1

. The degradation effects of the modified electrode on RO84 were evaluated systematically with different initial pH values

time durations

and amounts of CuNPs and MWCNT. The results suggested that the removal efficiency of RO84 was approximately 83% after 120 min of electrolysis in a phosphate buffer with pH 8.0 using a carbon ceramic electrode made with 4.0 wt% CuNPs and 4.0 wt% MWCNT. The possible mechanism of RO84 degradation was monitored by gas chromatography-mass spectrometry

and degradation pathways were proposed.

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