Hualing Duan, Kun Zhu, Houfang Lu, 等. CO2 absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. 中国化学工程学报(英文版), 2020,28(1):104-113. DOI: 10.1016/j.cjche.2019.03.031.
absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. 中国化学工程学报, 2020, 28(1): 104-113.
Hualing Duan, Kun Zhu, Houfang Lu, 等. CO2 absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. 中国化学工程学报(英文版), 2020,28(1):104-113. DOI: 10.1016/j.cjche.2019.03.031.DOI:
absorption performance in a rotating disk reactor using DBU-glycerol as solvent[J]. 中国化学工程学报, 2020, 28(1): 104-113.DOI: 10.1016/j.cjche.2019.03.031.
CO2 absorption performance in a rotating disk reactor using DBU-glycerol as solvent
Gas-liquid mass transfer of rotating disk reactor was studied in CO
2
absorption using 1
8-diazabicyclo-[5.4.0
]
-undec-7-ene (DBU)-glycerol solution as solvent. Effects of the rotating disk structure and various operation parameters on the CO
2
absorption rate and CO
2
removal efficiency were investigated. The rotating disk with optimal holes is conducive to mass transfer of CO
2
and the formation of thin liquid film at the opening increases the gas-liquid contact area. With the increase of rotating speed
the liquid flow pattern on the rotating disk surface changes from thin film flow to separated streams and creates extra liquid lines attached to the rim of the disk
which leads to a very complicated change on the CO
2
absorption rate and CO
2
removal efficiency. The overall gas-phase mass transfer coefficient increases 138% as the rotating speed increasing from 250 to 1400 r·min
-1
. Increasing temperature from 298 to 338 K can enhance the CO
2
absorption rate due to lowering the viscosity of the solvent. The rate-determined step for the absorption is focused on the gas side. The rotating disk reactor can effective
ly enhance the absorption of CO
2
with viscous DBU-glycerol solvents.
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相关作者
乔燕
闫方友
夏淑倩
马沛生
Liang Jin
Liu Shijie
Wang Haoliang
Li Xiangyang
相关机构
2 Key Laboratory for Green Chemical Technology of the State Education Ministry, School of Chemical Engineering and Technology, Tianjin University
State Key Laboratory of Petroleum Molecular & Process Engineering, Institute of Process Engineering, Chinese Academy of Sciences
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences
College of Chemistry and Chemical Engineering, Taiyuan University of Technology
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology