Ill-Min Chung, Seung-Hyun Kim, Venkatesan Hemapriya, 等. Inhibition behavior of Tragia involucrata L. phenolic compounds against acidic medium corrosion in low carbon steel surface[J]. 中国化学工程学报(英文版), 2019,27(3):717-725.
Ill-Min Chung, Seung-Hyun Kim, Venkatesan Hemapriya, Kathirvel Kalaiselvi, Mayakrishnan Prabakaran. Inhibition behavior of Tragia involucrata L. phenolic compounds against acidic medium corrosion in low carbon steel surface[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 717-725.
Ill-Min Chung, Seung-Hyun Kim, Venkatesan Hemapriya, 等. Inhibition behavior of Tragia involucrata L. phenolic compounds against acidic medium corrosion in low carbon steel surface[J]. 中国化学工程学报(英文版), 2019,27(3):717-725.DOI: 10.1016/j.cjche.2018.10.008.
Ill-Min Chung, Seung-Hyun Kim, Venkatesan Hemapriya, Kathirvel Kalaiselvi, Mayakrishnan Prabakaran. Inhibition behavior of Tragia involucrata L. phenolic compounds against acidic medium corrosion in low carbon steel surface[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 717-725.DOI: 10.1016/j.cjche.2018.10.008.
Inhibition behavior of Tragia involucrata L. phenolic compounds against acidic medium corrosion in low carbon steel surface
摘要
Abstract
The antioxidant and anticorrosive effect of Tragia involucrate L. (T. involucrate L.) was evaluated to aid in finding new compounds which can be used for various purposes. The total phenolic (TPC) and flavonoid content (TFC)
antioxidant activity (DPPH
reducing potential and phosphomolybdenum)
and electrochemical measurements
Fourier transform infrared (FT-IR)
UV-visible (UV-vis) spectral analysis
scanning electron microscopy/energydispersive X-ray spectroscopy (SEM-EDX) and atomic force microscopy (AFM) were done to analyze the potency and also the inhibition efficiency of T. involucrate L. against 1 mol·L
-1
HCl on low carbon steel. The TPC (145.21 mg GAE·g
-1
)
TFC (52.32 mg QCE·g
-1
) and antioxidant activities were found to be significant. The electrochemical studies performed by AC impedance measurements showed significant changes in impedance spectra without causing any change in Nyquist plots. An increase in charge transfer resistance (R
ct
) values
a blockage in active sites exhibiting cathodic and anodic inhibition shows the action of inhibitor on low carbon steel. This was later confirmed by FT-IR and UV-vis which
showed variation in absorption band at 270 nm and 273 nm (before immersion) and 208 and 281 nm (after immersion). The same was tested again by SEM-EDX through altered strength of iron and oxygen bands and using AFM by analyzing the change in average roughness values of low carbon steel before (61.65 nm) and after (97.87 nm) exposure to blank acid without inhibitor
while it was shifted to 81.58 nm in acid with inhibitor. All these results showed strong evidence adding values to T. involucrate L. plant extract in inhibiting corrosion on low carbon steel and by promoting antioxidant importance of the extract which helps in scavenging free radicals.
关键词
Keywords
references
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相关作者
Yueting Shi
Junhai Zhao
Lingli Chen
Hongru Li
Shengtao Zhang
Fang Gao
Hu Zhicheng
Ou Guofu
相关机构
College of Chemistry and Chemical Engineering, Chongqing University
Institute of Flow-Induced Corrosion, Changzhou University
School of Computer Science and Artificial Intelligence, Changzhou University
Faculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Persiaran Tun Khalil Yaakob
Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Persiaran Tun Khalil Yaakob