Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor

Peipei Li; Dazhi Zhang; Yunhui Xu; Caihua Ni; Gang Shi; Xinxin Sang

doi:10.1016/j.cjche.2018.09.014

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Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor

Materials and Product Engineering | Updated：2026-01-06

- Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor
- Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor
- 中国化学工程学报（英文版） 2019年27卷第3期页码：709-716
- Affiliations：
  
  2 Xuzhou College of Industrial Technology,Xuzhou,China,221140
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.09.014
  中图分类号：
- 纸质出版：2019
- Accepted：
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Peipei Li, Dazhi Zhang, Yunhui Xu, 等. Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor[J]. 中国化学工程学报（英文版）, 2019,27(3):709-716.

Peipei Li, Dazhi Zhang, Yunhui Xu, Caihua Ni, Gang Shi, Xinxin Sang. Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 709-716.
Peipei Li, Dazhi Zhang, Yunhui Xu, 等. Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor[J]. 中国化学工程学报（英文版）, 2019,27(3):709-716. DOI： 10.1016/j.cjche.2018.09.014.

Peipei Li, Dazhi Zhang, Yunhui Xu, Caihua Ni, Gang Shi, Xinxin Sang. Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 709-716. DOI： 10.1016/j.cjche.2018.09.014.

摘要

In this paper

nitrogen-doped hierarchical porous carbon (N-HPC) was prepared from polyaniline (PANI)/silica self-aggregates. H-bonding between N-H groups in aniline/PANI and -OH groups in nano silica temp

late led to a self-assembly type

which enabled the formation of uniform N-HPC nanoparticles. Silica self-aggregates provided macroporous channels resulted in a decreased diffusion distance. After removing the hard template

the N-HPC had a high surface area (899 m

·g

-1

). Owing to two co-existed synergetic energy-storage mechanisms and the hierarchical porous structure

the obtained N-HPC exhibited a high specific capacitance of 218.75 F·g

-1

at 0.5 A·g

-1

compared with the nonporous nitrogen-doped carbon (N-C) derived from pure PANI. Moreover

the N-HPC electrode demonstrated excellent cycle life

retaining 99% of its initial specific capacitance after 1000 cycles.

Abstract

In this paper

nitrogen-doped hierarchical porous carbon (N-HPC) was prepared from polyaniline (PANI)/silica self-aggregates. H-bonding between N\\H groups in aniline/PANI and\\OH groups in nano silica template led to a self-assembly type

which enabled the formation of uniform N-HPC nanoparticles. Silica self-aggregates provided macroporous channels resulted in a decreased diffusion distance. After removing the hard template

the N-HPC had a high surface area (899 m

·g

-1

). Owing to two co-existed synergetic energy-storage mechanisms and the hierarchical porous structure

the obtained N-HPC exhibited a high specific capacitance of 218.75 F·g

-1

at 0.5 A·g

-1

compared with the nonporous nitrogen-doped carbon (N-C) derived from pure PANI. Moreover

the N-HPC electrode demonstrated excellent cycle life

retaining 99% of its initial specific capacitance after 1000 cycles.

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