Lixiang Jiang, Chufu Li, Ming Xu, 等. Investigation on and industrial application of degrading of methanol feed in methanol to propylene process[J]. 中国化学工程学报(英文版), 2018,26(10):2102-2111.
Lixiang Jiang, Chufu Li, Ming Xu, Aihua Xing, Rui Feng, Jianjun Wu. Investigation on and industrial application of degrading of methanol feed in methanol to propylene process[J]. Chin.J.Chem.Eng., 2018, 26(10): 2102-2111.
Lixiang Jiang, Chufu Li, Ming Xu, 等. Investigation on and industrial application of degrading of methanol feed in methanol to propylene process[J]. 中国化学工程学报(英文版), 2018,26(10):2102-2111.DOI: 10.1016/j.cjche.2018.09.010.
Lixiang Jiang, Chufu Li, Ming Xu, Aihua Xing, Rui Feng, Jianjun Wu. Investigation on and industrial application of degrading of methanol feed in methanol to propylene process[J]. Chin.J.Chem.Eng., 2018, 26(10): 2102-2111.DOI: 10.1016/j.cjche.2018.09.010.
Investigation on and industrial application of degrading of methanol feed in methanol to propylene process
methanol to propylene (MTP) technology developed by Lurgi Company is adopted for commercial plants and refined methanol with the purity ≥ 99.85 wt% is required as the feed of MTP unit in Lurgi's technology. Therefore
high energy cost for refined methanol production is one of the bottlenecks to improve the economy of MTP technology. Reducing the grade of feed refined methanol may be an effective method to save energy and reduce operation costs in MTP process. In this work
experiments and process simulation were carried out to investigate the influence and feasibility of degrading the methanol feed. Experiments were conducted to investigate the influence of crude methanol feed on conversion and selectivity of MTP reaction as well as the performance of ZSM-5 catalyst. The experimental results showed that degrading the methanol feed had no obvious influence on the conversion and selectivity of MTP reactions and the catalyst deactivation was caused by the carbon accumulation and metals deposition on the active sites. The process simulation results showed that the influence on the conversion and selectivity as well as the stream load of MTP process wa
s negligible if 98mol% methanol was used as feed. Finally
industrial experiments were conducted by adjusting the operation parameters to degrade of feed methanol of the commercial 500 kt·a
-1
MTP unit of Ningmei Group in China. The results of industrial application illustrated that annually 180 kt fuel coal and 150 kt desalted water as well as1770 MW·h
-1
electricity would be saved when the water content increased from 0.01% to 0.4%. This work has identified the feasibility to improve MTP technology by degrading the methanol feed.
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相关作者
Xiaomin Qiu
Yuanyuan Shen
Zhengkun Hou
Qi Wang
Zhaoyou Zhu
Yinglong Wang
Jingwei Yang
Jun Gao
相关机构
College of Chemical and Environmental Engineering, Shandong University of Science and Technology
College of Chemical Engineering, Qingdao University of Science and Technology
Department of Earth Sciences, Utrecht University
Environmental Engineering Research Center (EERC), Sahand University of Technology, P.O.Box 51335-1996, Sahand New Town, Tabriz
Chemical Engineering Faculty, Sahand University of Technology, P.O.Box 51335-1996, Sahand New Town, Tabriz