Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models

Dewi Selvia Fardhyanti; Bayu Triwibowo; Heri Istanto; Muhammad Khusni Anajib; Amalia Larasati; Windy Oktaviani

doi:10.1016/j.cjche.2018.08.011

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Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models

Chemical Engineering Thermodynamics | Updated：2026-01-06

- Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models
- Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models
- 中国化学工程学报（英文版） 2019年27卷第2期页码：391-399
- Affiliations：
  
  Department of Chemical Engineering, Faculty of Engineering, Universitas Negeri Semarang, Semarang,Indonesia,50236
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.08.011
  中图分类号：
- 纸质出版：2019
- Accepted：
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Dewi Selvia Fardhyanti, Bayu Triwibowo, Heri Istanto, 等. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models[J]. 中国化学工程学报（英文版）, 2019,27(2):391-399.

Dewi Selvia Fardhyanti, Bayu Triwibowo, Heri Istanto, Muhammad Khusni Anajib, Amalia Larasati, Windy Oktaviani. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models[J]. Chin.J.Chem.Eng., 2019, 27(2): 391-399.
Dewi Selvia Fardhyanti, Bayu Triwibowo, Heri Istanto, 等. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models[J]. 中国化学工程学报（英文版）, 2019,27(2):391-399. DOI： 10.1016/j.cjche.2018.08.011.

Dewi Selvia Fardhyanti, Bayu Triwibowo, Heri Istanto, Muhammad Khusni Anajib, Amalia Larasati, Windy Oktaviani. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models[J]. Chin.J.Chem.Eng., 2019, 27(2): 391-399. DOI： 10.1016/j.cjche.2018.08.011.

摘要

Abstract

Utilization of biomass as a new and renewable energy source is being actively conducted by various parties. One of the technologies for utilizing or converting biomass as an energy source is pyrolysis

to convert biomass into a more valuable product which is bio-oil. Bio-oil is a condensed liquid from the vapor phase of biomass pyrolysis such as coconut shells and coffee shells. Biomass composition consisting of hemicellulose

cellulose

and lignin will oxidize to phenol which is the main content in bio-oil. The total phenolic compounds contained in bio-oil are 47.03% (coconut shell) and 45% (coffee shell). The content of phenol compounds in corrosive bio-oils still quite high

the use of this bio-oil directly will cause various difficulties in the combustion system due to high viscosity

low calorific value

corrosivity

and instability. Phenol compounds have some benefits as one of the compounds for floor cleaners and disinfectants which are contained in bio-oil. The correlation between experimental data and calculations shows that the UNIQUAC Functional-group Activity Coefficients (UNIFAC) equilibrium model can be used to predict the liquid-liquid equilibrium in the phenol extraction process of the coconut shell pyrolysis bio-oil. While the Non-Random Two Liquid (NRTL) equilibrium model can be used to predict liquid-liquid equilibrium in the extraction process of phenol from bio-oil pyrolysis of coffee shells.

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