Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment

Yiping Liu; Ya Zhang; Shuangqing Liu; Yuntao Lü; Ronghua Lin; Min Li; Xiaolan Liao; Xiaogang Li

doi:10.1016/j.cjche.2018.07.003

Your Location：

Home >

Browse articles >

Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment

Energy, Resources and Environmental Technology | Updated：2026-01-06

- Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment
- Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment
- 中国化学工程学报（英文版） 2018年26卷第10期页码：2185-2191
- Affiliations：
  
  1. 2 Institute for the Control of Agrochemicals,Hunan Province,Changsha,China,410005
  2. 3 Institute for the Control of Agrochemicals, Ministry of Agriculture and Rural Affairs,Beijing,China,100125
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.07.003
  中图分类号：
- 纸质出版：2018
- Accepted：
Scan QR Code
Yiping Liu, Ya Zhang, Shuangqing Liu, 等. Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment[J]. 中国化学工程学报（英文版）, 2018,26(10):2185-2191.

Yiping Liu, Ya Zhang, Shuangqing Liu, Yuntao Lü, Ronghua Lin, Min Li, Xiaolan Liao, Xiaogang Li. Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment[J]. Chin.J.Chem.Eng., 2018, 26(10): 2185-2191.
Yiping Liu, Ya Zhang, Shuangqing Liu, 等. Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment[J]. 中国化学工程学报（英文版）, 2018,26(10):2185-2191. DOI： 10.1016/j.cjche.2018.07.003.

Yiping Liu, Ya Zhang, Shuangqing Liu, Yuntao Lü, Ronghua Lin, Min Li, Xiaolan Liao, Xiaogang Li. Distribution and degradation kinetics of cyhalodiamide in Chinese rice field environment[J]. Chin.J.Chem.Eng., 2018, 26(10): 2185-2191. DOI： 10.1016/j.cjche.2018.07.003.

摘要

Abstract

Cyhalodiamide is a novel agrochemical which is effective against Lepidoptera pests

including Cnaphalocrocis medinalis

Chilo suppressalis

Pieris rapae

Plutella xylostella

Helicoverpa armigera

etc. In the study

a fast and accurate analytical method was developed to detect cyhalodiamide in Chinese typical rice field environment by a modified QuEChERS (Quick

Easy

Cheap

Effective

Rugged

Safe) method with UPLC-MS/MS (ultra-high performance chromatography-tandem mass spectrometry). The mean recoveries of cyhalodiamide varied from 73.5% to 107.5%

with the RSDs from 1.2% to 10.7%. The limits of determination (LODs) were 0.0005 mg·kg

-1

and the limits of quantitation (LOQs) were from 0.002 to 0.01 mg·kg

-1

in all five matrices. This method was used to determine cyhalodiamide residues for studies of the distribution and degradation kinetics in rice field environment. The field trials results showed that cyhalodiamide was easily degradable and the half-lives were 4.2-13.6 d in rice straw

8.77 d in paddy soil and 5.37-8.45 d in paddy water

respectively. The final residues of cyhalodiamide in brown rice were below 0.35 mg·kg

-1

. The used dosage

of 33.75 g·hm

-2

with pre-harvest interval (PHI) of 21 d and the maximum residue limit (MRL) of cyhalodiamide in rice at 0.1 mg·kg

-1

were recommended

which would be safe to human health and environment. The developed analytical method will be useful to monitor cyhalodiamide residues and safety evaluation in rice environment.

关键词

Keywords

references

浏览量

217

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Insight into the degradation mechanism of cefixime under crystallization condition

Experimental and numerical studies of holdup and velocity behavior for inclined bubbly oil-water pipe flows

Enhanced plasma-catalytic steam reforming of methane to methanol on a hydrophobically modified Cu/silicalite-1 catalyst

Biochar as a structure-tunable stationary phase for column chromatographic fractionation of bio-oil

Enhanced mass transfer in flexible electrodes of open-pore cobalt disulfide nanosheets supported on sulfur-doped carbon fibers for efficient zinc-air batteries