Dan Liang, Yufeng Hu, Weiting Ma, 等. Concentration of linoleic acid from cottonseed oil by starch complexation[J]. 中国化学工程学报(英文版), 2019,27(4):845-849.
Dan Liang, Yufeng Hu, Weiting Ma, Zhengtang Zhao, Siqi Jiang, Yichuan Wang, Xianming Zhang. Concentration of linoleic acid from cottonseed oil by starch complexation[J]. Chinese Journal of Chemical Engineering, 2019, 27(4): 845-849.
Dan Liang, Yufeng Hu, Weiting Ma, 等. Concentration of linoleic acid from cottonseed oil by starch complexation[J]. 中国化学工程学报(英文版), 2019,27(4):845-849.DOI: 10.1016/j.cjche.2018.07.001.
Dan Liang, Yufeng Hu, Weiting Ma, Zhengtang Zhao, Siqi Jiang, Yichuan Wang, Xianming Zhang. Concentration of linoleic acid from cottonseed oil by starch complexation[J]. Chinese Journal of Chemical Engineering, 2019, 27(4): 845-849.DOI: 10.1016/j.cjche.2018.07.001.
Concentration of linoleic acid from cottonseed oil by starch complexation
摘要
Abstract
The extraction of linoleic acid from fatty acids (FA) of the cottonseed oil using starch-FA complexes was developed for the first time. We showed that starch can form inclusion complexes of different strengths with FA and that the different strengths stem from the differences in chain length
degree of unsaturation
and position of double bonds of FA. The optimal separation conditions were determined as follows:The inclusion temperature is 69℃
the inclusion time is 30 min
the starch/FA mass ratio is 10:1
and the ratio of the volume of methanol-water solution and the mass of FA is 18:1. Compared to urea inclusion complexation
starch complexation has milder reaction temperature and shorter reaction time. Under these conditions
linoleic acid can be concentrated from 38.9% to 70.04% by one-off extraction. Moreover
the experimental results demonstrate the almost perfect reusability of starch. These results show that starch complexation is a promising method that can be used to obtain highly concentrated linoleic acid from cottonseed oil.
关键词
Keywords
references
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相关作者
Zhongwei Tan
Xingguo Xu
Yu Wan
Chengjun Kang
Zhaoqiang Zhang
Zhenxia Zhao
Fang Shen
Kungang Chai
相关机构
School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4
Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-sen University
College of Chemistry and Chemical Engineering, Nanjing Tech University