Mahdi Abdi-Khanghah, Mostafa Adelizadeh, Zahra Naserzadeh, 等. n-Decane hydro-conversion over bi-and tri-metallic Al-HMS catalyst in a mini-reactor[J]. 中国化学工程学报(英文版), 2018,(6):1330-1339.
Mahdi Abdi-Khanghah, Mostafa Adelizadeh, Zahra Naserzadeh, et al. n-Decane hydro-conversion over bi-and tri-metallic Al-HMS catalyst in a mini-reactor[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1330-1339.
Mahdi Abdi-Khanghah, Mostafa Adelizadeh, Zahra Naserzadeh, 等. n-Decane hydro-conversion over bi-and tri-metallic Al-HMS catalyst in a mini-reactor[J]. 中国化学工程学报(英文版), 2018,(6):1330-1339.DOI: 10.1016/j.cjche.2018.04.007.
Mahdi Abdi-Khanghah, Mostafa Adelizadeh, Zahra Naserzadeh, et al. n-Decane hydro-conversion over bi-and tri-metallic Al-HMS catalyst in a mini-reactor[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1330-1339.DOI: 10.1016/j.cjche.2018.04.007.
n-Decane hydro-conversion over bi-and tri-metallic Al-HMS catalyst in a mini-reactor
Bi-metallic (Pt-Sn and Sn-Ni) and tri-metallic (Pt-Sn-Ni) catalysts
supported on Al-containing hexagonal mesoporous silica (Al-HMS) (Si/Al=20) materials
were synthesized. N
2
adsorption-desorption
X-ray diffraction (XRD)
Brunauer-Emmett-Teller (BET) test
and temperature programed desorption (NH3-TPD) were used to characterize physicochemical characteristics and textural properties of the Al-HMS catalysts. Catalytic performances on hydro-cracking of n-decane at different reaction conditions were studied in a microreactor. Comparison between Pt-Sn
Sn-Ni and Pt-Sn-Ni catalyst under different hydro-cracking conditions was made. The experimental results indicate that the proper balance between the acid and metal functions is the key in synthesizing a catalyst with a better performance in hydro-cracking. Tri-metallic catalyst exhibits the best catalytic performance in n-decane hydro-cracking than two bi-metallic catalysts.
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