The study of methanol aromatization on transition metal modified ZSM-5 catalyst

Keming Ji; Jiayao Xun; Ping Liu; Qingwen Song; Junhua Gao; Kan Zhang; Jingyuan Li

doi:10.1016/j.cjche.2018.03.024

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The study of methanol aromatization on transition metal modified ZSM-5 catalyst

Catalysis, Kinetics and Reaction Engineering | Updated：2026-01-06

- The study of methanol aromatization on transition metal modified ZSM-5 catalyst
- The study of methanol aromatization on transition metal modified ZSM-5 catalyst
- 中国化学工程学报（英文版） 2018年26卷第9期页码：1949-1953
- Affiliations：
  
  State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences,Taiyuan,China,030001
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.03.024
  中图分类号：
- 纸质出版：2018
- Accepted：
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Keming Ji, Jiayao Xun, Ping Liu, 等. The study of methanol aromatization on transition metal modified ZSM-5 catalyst[J]. 中国化学工程学报（英文版）, 2018,26(9):1949-1953.

Keming Ji, Jiayao Xun, Ping Liu, Qingwen Song, Junhua Gao, Kan Zhang, Jingyuan Li. The study of methanol aromatization on transition metal modified ZSM-5 catalyst[J]. Chin.J.Chem.Eng., 2018, 26(9): 1949-1953.
Keming Ji, Jiayao Xun, Ping Liu, 等. The study of methanol aromatization on transition metal modified ZSM-5 catalyst[J]. 中国化学工程学报（英文版）, 2018,26(9):1949-1953. DOI： 10.1016/j.cjche.2018.03.024.

Keming Ji, Jiayao Xun, Ping Liu, Qingwen Song, Junhua Gao, Kan Zhang, Jingyuan Li. The study of methanol aromatization on transition metal modified ZSM-5 catalyst[J]. Chin.J.Chem.Eng., 2018, 26(9): 1949-1953. DOI： 10.1016/j.cjche.2018.03.024.

摘要

Abstract

In this article

transition metals of Cu

La and Zn were used as adjuvant to prepare modified HZSM-5 by impregnation method. The catalysts were characterized by XRD

BET

-TPD and Py-IR to reveal the microstructure and acid property. The catalysis performances of methanol aromatization of catalysts were investigated in a fixed-bed reactor. The results show that the strength and distribution of acid center of these catalysts are significantly influenced by the species of transition metal. There are more mediate strong Lewis acid center in Zn modified HZSM-5 catalyst and therefore exhibits higher selectivity to aromatic

benzene

toluene and xylenes in the MTA reaction.

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