One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Chongwen Jiang; Jundong Zhu; Bing Wang; Lu Li; Hong Zhong

doi:10.1016/j.cjche.2018.02.031

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One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Catalysis | Updated：2026-01-06

- One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6
- One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6
- 中国化学工程学报（英文版） 2018年第6期页码：1270-1277
- Affiliations：
  
  1. College of Chemistry and Chemical Engineering, Central South University,Changsha,China,410083
  2. 2 Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University,Changsha,China,410083
- Author bio：
- Funds：
  
  Supported by the National Natural Science Foundation of China (21476267), the China-Japan International Cooperation Project (2013DFG50150) and the Hunan Provincial Science and Technology Department Plan Project (2016TP1007).
- DOI：10.1016/j.cjche.2018.02.031
  中图分类号：
- 纸质出版：2018
- Accepted：
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Chongwen Jiang, Jundong Zhu, Bing Wang, 等. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. 中国化学工程学报（英文版）, 2018,(6):1270-1277.

Chongwen Jiang, Jundong Zhu, Bing Wang, et al. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1270-1277.
Chongwen Jiang, Jundong Zhu, Bing Wang, 等. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. 中国化学工程学报（英文版）, 2018,(6):1270-1277. DOI： 10.1016/j.cjche.2018.02.031.

Chongwen Jiang, Jundong Zhu, Bing Wang, et al. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, (6): 1270-1277. DOI： 10.1016/j.cjche.2018.02.031.

摘要

Abstract

Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method. Various characterization techniques confirm that highly distributed ZrO

nanoparticles and multicoordinated Zr

species are incorporated in the mesoporous composites. One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system. The effects of temperature

reaction time

catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated. It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system

respectively. Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.

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