Kinetic contribution of CO<sub>2</sub>/O<sub>2</sub> additive in methane conversion activated by non-equilibrium plasmas

Qi Chen; Jintao Sun; Xiaojun Zhang

doi:10.1016/j.cjche.2018.01.006

Your Location：

Home >

Browse articles >

Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas

Catalysis, Kinetics and Reaction Engineering | Updated：2026-01-06

- Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas
- Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas
- 中国化学工程学报（英文版） 2018年26卷第5期页码：1041-1050
- Affiliations：
  
  School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University,Beijing,China,100044
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2018.01.006
  中图分类号：
- 纸质出版：2018
- Accepted：
Scan QR Code
Qi Chen, Jintao Sun, Xiaojun Zhang. Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas[J]. 中国化学工程学报（英文版）, 2018,26(5):1041-1050. DOI: 10.1016/j.cjche.2018.01.006.

/O
Qi Chen, Jintao Sun, Xiaojun Zhang. Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas[J]. 中国化学工程学报（英文版）, 2018,26(5):1041-1050. DOI: 10.1016/j.cjche.2018.01.006. DOI：

/O DOI： 10.1016/j.cjche.2018.01.006.

摘要

Abstract

A temperature-controlled and pressure-controlled coaxial dielectric barrier discharge (DBD) reactor was developed to decouple the thermal and kinetic effects of radio frequency (RF) discharge on methane conversion

and further to compare the kinetic behaviors of the mechanistically similar reactions of methane conversion with O

and CO

additives. A kinetic mechanism for RF plasma assisted methane conversion was assembled. The formation of products in the RF plasma reactor was measured with Gas Chromatography (GC-TCD) and the data were used to validate the kinetic model. The experimental and computational results showed the different kinetic roles of carbon dioxide and oxygen additives in methane conversion

due to the different dissociation and ionization energy of the two additive gases

as well as the thus produced electron energy distribution function (EEDF). Fuel oxidation by plasma generated O

)

) and O

in partial oxidation of methane was observed essential for methane consumption

which resulted in

an increase in methane conversion rate

compared to pure methane pyrolysis and dry reforming of methane with CO

additive. It was also found that dry reforming of methane with CO

was by far the easier to produce the syngas as well as C

hydrocarbon species

due to the weak oxidation ability of CO

and also the significant deposition of the electron energy on CH

dissociation in a dry reforming discharge mixture. This kinetic study produced comparative data to demonstrate the contribution of CO

additive in non-equilibrium plasma assisted methane conversion.

关键词

Keywords

references

浏览量

309

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Unraveling the methane decomposition mechanism on Fe-Ni-Ca-O composite catalysts: A combined density functional theory and microdynamic study

Thermal decomposition behavior and kinetics of magnesite under carbon dioxide atmosphere

Substrate-free spatial separation pyrolysis for uniform iron/cobalt/nickel-based nanocatalysts enabling high-performance rechargeable zinc-air batteries

Selective catalytic deoxygenation of 1-octanol from Fischer-Tropsch C10 mixed oil

Heterogeneously catalyzed self-condensation of n-butanal

Kinetic contribution of CO2/O2 additive in methane conversion activated by non-equilibrium plasmas

Kinetic contribution of CO2/O2 additive in methane conversion activated by non-equilibrium plasmas

DOI：10.1016/j.cjche.2018.01.006

摘要

Abstract

关键词

Keywords

references

Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas

Kinetic contribution of CO₂/O₂ additive in methane conversion activated by non-equilibrium plasmas