Farshid Zargari, Delara Mohammad-Aghaie, Maryam Lotfi, 等. Transport properties of dilute ammonia-noble gas mixtures from new intermolecular potential energy functions[J]. 中国化学工程学报(英文版), 2017,25(12):1727-1734.
Farshid Zargari, Delara Mohammad-Aghaie, Maryam Lotfi, Masoume Ghorbanipour, Mohammad Mehdi Alavianmehr, Omolbanin Shahraki. Transport properties of dilute ammonia-noble gas mixtures from new intermolecular potential energy functions[J]. Chin.J.Chem.Eng., 2017, 25(12): 1727-1734.
Farshid Zargari, Delara Mohammad-Aghaie, Maryam Lotfi, 等. Transport properties of dilute ammonia-noble gas mixtures from new intermolecular potential energy functions[J]. 中国化学工程学报(英文版), 2017,25(12):1727-1734.DOI: 10.1016/j.cjche.2017.07.007.
Farshid Zargari, Delara Mohammad-Aghaie, Maryam Lotfi, Masoume Ghorbanipour, Mohammad Mehdi Alavianmehr, Omolbanin Shahraki. Transport properties of dilute ammonia-noble gas mixtures from new intermolecular potential energy functions[J]. Chin.J.Chem.Eng., 2017, 25(12): 1727-1734.DOI: 10.1016/j.cjche.2017.07.007.
Transport properties of dilute ammonia-noble gas mixtures from new intermolecular potential energy functions
Previously we have determined the dilute mixture transport properties of slightly polar fluorocarbons using the inverted intermolecular potential energies (Ind. Eng. Chem. Res. 45 (2006) 9211-9223). In the present paper
the corresponding states correlations for reduced viscosity collision integrals were employed to obtain effective unlike interaction potential models for dilute binarymixtures of highly polar molecule ammonia with noble gases. The inverted potentials were fitted to the Morse-Spline-van der Waals (MSV)
model potential. The method of least-squares fitting was then applied to identify best consistence force parameters for each ammonia-noble gas mixture
taking advantage of experimental viscosities
diffusion coefficients and thermal conductivities. The proposed potential modelswere compared with those obtained fromother sources
in order to assess the extent of their validity. The potentials were later employed to calculate transport properties of the studied mixtures. Then
results were compared with those reported in the literature
which led to the acceptable agreement.
Abstract
Previously we have determined the dilute mixture transport properties of slightly polar fluorocarbons using the inverted intermolecular potential energies (Ind. Eng. Chem. Res. 45 (2006) 9211-9223). In the present paper
the corresponding states correlations for reduced viscosity collision integrals were employed to obtain effective unlike interaction potential models for dilute binarymixtures of highly polar molecule ammonia with noble gases. The inverted potentials were fitted to the Morse-Spline-van der Waals (MSV)
model potential. The method of least-squares fitting was then applied to identify best consistence force parameters for each ammonia-noble gas mixture
taking advantage of experimental viscosities
diffusion coefficients and thermal conductivities. The proposed potential modelswere compared with those obtained fromother sources
in order to assess the extent of their validity. The potentials were later employed to calculate transport properties of the studied mixtures. Then
results were compared with those reported in the literature
which led to the acceptable agreement.
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相关作者
Khatereh Khanlarzadeh
Hossein Iloukhani
Hadi Taheri Parsa
Fang Zhu
Sufang Wang
Qi Tian
Qilong Ge
Qingjie Guo
相关机构
Department of Research and Development, Reference Analytical Chemistry Lab., Hamedan
Department of Physical Chemistry, Faculty of Chemistry and Petroleum Science, Bu-Ali Sina University, Hamedan
College of Civil Engineering, Taiyuan University of Technology
Department of Architecture and Environmental Engineering, Taiyuan College
College of Environmental Science and Engineering, Taiyuan University of Technology