Le Wu, Xiaoqiang Liang, Lixia Kang, 等. Integration strategies of hydrogen network in a refinery based on operational optimization of hydrotreating units[J]. 中国化学工程学报(英文版), 2017,25(8):1061-1068.
Le Wu, Xiaoqiang Liang, Lixia Kang, Yongzhong Liu. Integration strategies of hydrogen network in a refinery based on operational optimization of hydrotreating units[J]. , 2017, 25(8): 1061-1068.
Le Wu, Xiaoqiang Liang, Lixia Kang, 等. Integration strategies of hydrogen network in a refinery based on operational optimization of hydrotreating units[J]. 中国化学工程学报(英文版), 2017,25(8):1061-1068.DOI: 10.1016/j.cjche.2017.01.003.
Le Wu, Xiaoqiang Liang, Lixia Kang, Yongzhong Liu. Integration strategies of hydrogen network in a refinery based on operational optimization of hydrotreating units[J]. , 2017, 25(8): 1061-1068.DOI: 10.1016/j.cjche.2017.01.003.
Integration strategies of hydrogen network in a refinery based on operational optimization of hydrotreating units
摘要
Abstract
Inferior crude oil and fuel oil upgrading lead to escalating increase of hydrogen consumption in refineries. It is imperative to reduce the hydrogen consumption for energy-saving operations of refineries. An integration strategy of hydrogen network and an operational optimization model of hydrotreating (HDT) units are proposed based on the characteristics of reaction kinetics of HDT units. By solving the proposed model
the operating conditions of HDT units are optimized
and the parameters of hydrogen sinks are determined by coupling hydrodesulfurization (HDS)
hydrodenitrification (HDN) and aromatic hydrogenation (HDA) kinetics. An example case of a refinery with annual processing capacity of eight million tons is adopted to demonstrate the feasibility of the proposed optimization strategies and the model. Results show that HDS
HDN and HDA reactions are the major source of hydrogen consumption in the refinery. The total hydrogen consumption can be reduced by 18.9% by applying conventional hydrogen network optimization model. When the hydrogen network is optimized after the operational optimization of HDT units is performed
the hydrogen consumption is reduced by 28.2%. When the benefit of the fuel gas recovery is further cons
idered
the total annual cost of hydrogen network can be reduced by 3.21×10
7
CNY·a
-1
decreased by 11.9%. Therefore
the operational optimization of the HDT units in refineries should be imposed to determine the parameters of hydrogen sinks base on the characteristics of reaction kinetics of the hydrogenation processes before the optimization of the hydrogen network is performed through the source-sink matching methods.
关键词
Keywords
references
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相关作者
Xuexue Jia
Guilian Liu
Han Rui
Guan Qingshan
Gu Leqi
Sun Xiaoyan
Tophet Wongladprom
Vissanu Meeyoo
相关机构
School of Chemical Engineering and Technology, Xi'an Jiaotong University
College of Chemical Engineering, Qingdao University of Science and Technology
Anhui Metaenergy Technologies Co., Ltd
Center of Ionic Liquid and Green Energy, Beijing Key Laboratory of Solid State Battery and Energy Storage Process, State Key Laboratory of Mesoscience and Engineering, Institute of Process Engineering, Chinese Academy of Sciences
Center for Advanced Materials and Environmental Research, Mahanakorn University of Technology