Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study

Zhen Song; Dian Yu; Qian Zeng; Jingjing Zhang; Hongye Cheng; Lifang Chen; Zhiwen Qi

doi:10.1016/j.cjche.2016.08.029

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Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study

Selected Papers from the International Chemical Separation Technology Conference (ICSTC) | Updated：2026-01-06

- Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study
- Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study
- 中国化学工程学报（英文版） 2017年25卷第2期页码：159-165
- Affiliations：
  
  Max Planck Partner Group at the State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology,Shanghai,China,200237
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.08.029
  中图分类号：
- 纸质出版：2017
- Accepted：
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Zhen Song, Dian Yu, Qian Zeng, 等. Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study[J]. 中国化学工程学报（英文版）, 2017,25(2):159-165.

Zhen Song, Dian Yu, Qian Zeng, Jingjing Zhang, Hongye Cheng, Lifang Chen, Zhiwen Qi. Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study[J]. , 2017, 25(2): 159-165.
Zhen Song, Dian Yu, Qian Zeng, 等. Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study[J]. 中国化学工程学报（英文版）, 2017,25(2):159-165. DOI： 10.1016/j.cjche.2016.08.029.

Zhen Song, Dian Yu, Qian Zeng, Jingjing Zhang, Hongye Cheng, Lifang Chen, Zhiwen Qi. Effect of water on extractive desulfurization of fuel oils using ionic liquids: A COSMO-RS and experimental study[J]. , 2017, 25(2): 159-165. DOI： 10.1016/j.cjche.2016.08.029.

摘要

Abstract

When evaluating ionic liquids (ILs) for extractive desulfurization (EDS) of fuel oils

the inevitable presence of water in the system may have a significant and in many cases strongly negative effect. However

few studies have considered this particular issue and a promoted water effect on EDS is scarcely reported. In this work

COSMO-RS was firstly employed to calculate the capacity and selectivity for EDS of various IL/H

O mixtures

which cover different IL characters and a wide water concentration range. Experiments were then conducted with a representative IL[C

MIM

]

whose stable and even promoted extraction performance with a small amount of water was suggested by COSMO-RS. Through analyses of the desulfurization ratio

the crosssolubility and the water content in the desulfurized fuel

the promoted effect of water within a certain range (10 wt%) was experimentally demonstrated. Moreover

such effect of water was explained combining the viscosity

the solvent-solute interactions and the COSMO-RS based analysis.

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