Tianyu Guo, Jianping Du, Jinting Wu, 等. Enhanced properties of solid solution (CeZr)O2 modified with metal oxides for catalytic oxidation of low-concentration methane[J]. 中国化学工程学报(英文版), 2017,25(2):187-192. DOI: 10.1016/j.cjche.2016.07.016.
modified with metal oxides for catalytic oxidation of low-concentration methane[J]. , 2017, 25(2): 187-192.
Tianyu Guo, Jianping Du, Jinting Wu, 等. Enhanced properties of solid solution (CeZr)O2 modified with metal oxides for catalytic oxidation of low-concentration methane[J]. 中国化学工程学报(英文版), 2017,25(2):187-192. DOI: 10.1016/j.cjche.2016.07.016.DOI:
modified with metal oxides for catalytic oxidation of low-concentration methane[J]. , 2017, 25(2): 187-192.DOI: 10.1016/j.cjche.2016.07.016.
Enhanced properties of solid solution (CeZr)O2 modified with metal oxides for catalytic oxidation of low-concentration methane
摘要
Abstract
The solid solution (CeZr)O
2
catalyst was synthesized
and it wasmodified with metal oxides by incipient impregnation. Morphology and structure were characterized by X-ray diffraction
transmission electronmicroscope
nitrogen ad/desorption and H
2
-temperature program reduction techniques. The catalytic properties of methane oxidation were also investigated. The results showed that solid solution possessed a mesoporous structure and exhibited excellent catalytic performance. The activity of solid solution was improved effectively by nickel doping
and the optimal loading is 15 wt%. The stability of (CeZr)O
2
and modified (CeZr)O
2
indicated that the structure of pristine solid solution played a key role in promoting molecules diffusion and spatial confining oxide particle sintering.
关键词
Keywords
references
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Preparation of anodic catalysts via in situ exsolution of Pt nanoparticles for a methane oxidation enhanced SOEC process
Preparation of MoO3/γ-Al2O3 sulfur-resistant methanation catalyst with segmented plasma fluidized bed
Oxygen vacancies enriched Ni-Co/SiO2@CeO2 redox catalyst for cycling methane partial oxidation and CO2 splitting
Imidazole-based porous organic polymers featuring hydrogen bond donors as environmentally friendly heterogeneous catalysts for efficient CO2 conversion
Impact of sugar type on thiophene hydrodesulfurization performance of three-dimensional porous CoMo bulk catalysts prepared via the sugar foaming method
相关作者
Liming Zhou
Kejing Wu
Qiang Hu
Houfang Lu
Bin Liang
Baowei Wang
Jiangzhou Kong
Xiaoyan Li
相关机构
School of Chemical Engineering, Sichuan University
Institute of New Energy and Low-Carbon Technology, Sichuan University
Sichuan Energy Internet Research Institute Tsinghua University
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology