Modification of methyl oleate for silicon-based biological lubricating base oil

Shixing Cui; Zhi Yun; Xia Gui

doi:10.1016/j.cjche.2016.06.001

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Modification of methyl oleate for silicon-based biological lubricating base oil

Energy, Resources and Environmental Technology | Updated：2026-01-06

- Modification of methyl oleate for silicon-based biological lubricating base oil
- Modification of methyl oleate for silicon-based biological lubricating base oil
- 中国化学工程学报（英文版） 2017年25卷第1期页码：130-136
- Affiliations：
  
  College of Chemistry and Chemical Engineering, Nanjing University of Technology,Nanjing,China,210009
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.06.001
  中图分类号：
- 纸质出版：2017
- Accepted：
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Shixing Cui, Zhi Yun, Xia Gui. Modification of methyl oleate for silicon-based biological lubricating base oil[J]. 中国化学工程学报（英文版）, 2017,25(1):130-136.

Shixing Cui, Zhi Yun, Xia Gui. Modification of methyl oleate for silicon-based biological lubricating base oil[J]. , 2017, 25(1): 130-136.
Shixing Cui, Zhi Yun, Xia Gui. Modification of methyl oleate for silicon-based biological lubricating base oil[J]. 中国化学工程学报（英文版）, 2017,25(1):130-136. DOI： 10.1016/j.cjche.2016.06.001.

Shixing Cui, Zhi Yun, Xia Gui. Modification of methyl oleate for silicon-based biological lubricating base oil[J]. , 2017, 25(1): 130-136. DOI： 10.1016/j.cjche.2016.06.001.

摘要

Abstract

A new kind of silicon-based biological lubricating base oil with good viscosity-temperature behavior

viscosity index

thermostability

oxidation stability and wear resistance performance was synthesized as a derivative of methyl oleate. Trimethylsilylation reaction was introduced to further improve methyl oleate oxidation stability and lubricity after epoxidation and open-ring reactions. The order of effectiveness of acid binding agent was

-diisopropylethylamine (DIEA) pyridine diethylamine triethylamine

and the effects of various parameters on the trimethylsilylation reaction as well as on the silicon-oxygen bond stability and reaction yield were studied. A maximum yield of 34.54% was achieved at hydroxyl/trimethyl chlorosilane/DIEA molar ratio of 1:1.25:1

reaction temperature 40℃

reaction time 1.5 h.

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