Synthesis and characterization of copolymers of poly(<i>m</i>-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation

Fenglei Bi; Jianqiang Shao; Zhenhao Xi; Ling Zhao; Di Liu

doi:10.1016/j.cjche.2016.04.003

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Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation

Materials and Product Engineering | Updated：2026-01-06

- Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation
- Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation
- 中国化学工程学报（英文版） 2016年24卷第9期页码：1290-1297
- Affiliations：
  
  1. Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, East China University of Science and Technology,Shanghai,China,200237
  2. Beijing Sanlian Hope Shin-Gosen Technical Service Co., Ltd.,Beijing,China,100102
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.04.003
  中图分类号： 10.1016/j.cjche.2016.04.003
- 纸质出版：2016
- Accepted：
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Fenglei Bi, Jianqiang Shao, Zhenhao Xi, 等. Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation[J]. 中国化学工程学报（英文版）, 2016,24(9):1290-1297. DOI: 10.1016/j.cjche.2016.04.003.

-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation[J]. , 2016, 24(9): 1290-1297.
Fenglei Bi, Jianqiang Shao, Zhenhao Xi, 等. Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation[J]. 中国化学工程学报（英文版）, 2016,24(9):1290-1297. DOI: 10.1016/j.cjche.2016.04.003. DOI：

-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation[J]. , 2016, 24(9): 1290-1297. DOI： 10.1016/j.cjche.2016.04.003.

摘要

中图分类号:

Abstract

Poly(

-xylylene adipamide)/poly(ethylene terephthalate) (MXD6/PET) copolymers are synthesized by melt copolycondensation with 1-5 wt% low molecular weight PET oligomers into the MXD6 oligomers at 260℃. FR-IR and

H NMR analysis results indicate that the interchange reaction has occurred between MXD6 oligomers and PET oligomers. The thermal behavior of copolymers shows that the melting temperature of MXD6/PET copolymers decreases with the increasing of amount of PET oligomers

while the crystallization temperature accordingly increases. And the equilibrium temperature

is evaluated to be 251.8℃ for the copolymers with 5 wt% PET oligomer adding

which is very close to that of neat MXD6. The tensile and impact strength of MXD6/PET copolymers are significantly improved than that of pure MXD6 by mechanical properties test

and the microfibril structure in the impact fracture sample's surface reveals the feature of ductile fracture.

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Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation

Synthesis and characterization of copolymers of poly(m-xylylene adipamide) and poly(ethylene terephthalate) oligomers by melt copolycondensation

DOI：10.1016/j.cjche.2016.04.003

摘要

Abstract

关键词

Keywords

references