Seyed Hossein Mazloumi. Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state[J]. 中国化学工程学报(英文版), 2016,24(10):1456-1463.
Seyed Hossein Mazloumi. Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state[J]. , 2016, 24(10): 1456-1463.
Seyed Hossein Mazloumi. Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state[J]. 中国化学工程学报(英文版), 2016,24(10):1456-1463.DOI: 10.1016/j.cjche.2016.04.002.
Seyed Hossein Mazloumi. Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state[J]. , 2016, 24(10): 1456-1463.DOI: 10.1016/j.cjche.2016.04.002.
Correlation of the mean activity coefficient of aqueous electrolyte solutions using an equation of state
Accurate calculation of thermodynamic properties of electrolyte solution is essential in the design and optimization of many processes in chemical industries. A new electrolyte equation of state is developed for aqueous electrolyte solutions. The Carnahan-Starling repulsive model and an attractive term based on square-well potential are adopted to represent the short range interaction of ionic and molecular species in the new electrolyte EOS. The long range interaction of ionic species is expressed by a simplified version ofMean Spherical Approximation theory (MSA). The newequation of state also contains a Born termfor charging free energy of ions. Three adjustable parameters of new eEOS per each electrolyte solution are size parameter
square-well potential depth and square-well potential interaction range. The new eEOS is applied for correlation of mean activity coefficient and prediction of osmotic coefficient of various strong aqueous electrolyte solutions at 25℃ and 0.1 MPa. In addition
the extension of the new eEOS for correlation of mean activity coefficient and solution density of a few aqueous electrolytes at temperature range of 0 to 100℃ is carried out.
关键词
Keywords
references
The trial reading is over, you can activate your VIP account to continue reading.
Experimental results for the vapor-liquid equilibria of (formaldehyde + 1,3,5-trioxane + methanol + salt + water) systems and comparison with predictions
Modeling for mean ion activity coefficient of strong electrolyte system with new boundary conditions and ion-size parameters
Measurement and Modeling of Vapor-Liquid Equilibrium for Ternary System Water + 2-Propanol + 1-Butyl-3-methylimidazolium Chloride
Effect of Mono- and Di-ethanolammonium Formate Ionic Liquids on the Volatility of Water, Ethanol, and Methanol
Vapor-Liquid Equilibrium Measurements and Modeling for Ternary System Water+Ethanol+1-Butyl-3-methylimidazolium Acetate
相关作者
Shuqin Mo
Zhichang Liu
Yufeng Hu
Mengchen Li
Xianming Zhang
Tao Fang
Miyi Li
邓东顺
相关机构
State Key Laboratory of Heavy Oil Processing and High Pressure Fluid Phase Behavior&Property Research Laboratory, China University of Petroleum
School of Chemical Engineering, Ordos Institute of Technology
PetroChina Petrochemical Research Institute Science Base PetroChina
2 Beijing Institute of Aerospace Testing Technology
Zhejiang Province Key Laboratory of Biofuel, College of Chemical Engineering and Material Science, Zhejiang University of Technology