Zhixi Gan, Zheng Cui, Hairong Yue, 等. An efficient methodology for utilization of K-feldspar and phosphogypsum with reduced energy consumption and CO2 emissions[J]. 中国化学工程学报(英文版), 2016,24(11):1541-1551. DOI: 10.1016/j.cjche.2016.04.001.
emissions[J]. Chinese Journal of Chemical Engineering, 2016, 24(11): 1541-1551.
Zhixi Gan, Zheng Cui, Hairong Yue, 等. An efficient methodology for utilization of K-feldspar and phosphogypsum with reduced energy consumption and CO2 emissions[J]. 中国化学工程学报(英文版), 2016,24(11):1541-1551. DOI: 10.1016/j.cjche.2016.04.001.DOI:
and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an efficient methodology via the co-reaction of K-feldspar and phosphogypsum for the extraction of soluble potassium salts and recovery of SO
2
with reduced CO
2
emission and energy consumption. The results of characterization and reactivity evaluation indicated that the partial melting of K-feldspar and phosphogypsum in the hightemperature co-reaction significantly facilitated the reduction of phosphogypsum to SO
2
and the exchange of K
+
(K-feldspar) with Ca
2+
(CaSO
4
in phosphogypsum). The reaction parameters were systematically investigated with the highest sulfur recovery ratio of ~60% and K extraction ratio of ~87.7%. This novel methodology possesses an energy consumption reduction of ~28% and CO
2
emission reduction of ~55% comparing with the present typical commercial technologies for utilization of K-feldspar and the treatment of phosphogypsum.
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相关作者
Ge Zhaoshuo
Bao Lixia
Lv Yangping
Wu Yiheng
Shi Daxin
Liu Qi
Wu Qin
Chen Kangcheng
相关机构
Beijing Key Laboratory for Chemical Power Source and Green Catalysis, School of Chemistry and Chemical Engineering, Beijing Institute of Technology
Analysis and Testing Center, Beijing Institute of Technology
State Key Laboratory of Heavy Oil Processing, China University of Petroleum Beijing
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University