Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO<sub>3</sub> by molten salt electrolysis

WeiWeng; Mingyong Wang; Xuzhong Gong; ZhiWang; Zhancheng Guo

doi:10.1016/j.cjche.2016.01.006

Your Location：

Home >

Browse articles >

Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis

第25届中国过程控制会议专栏 | Updated：2026-01-06

- Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis
- Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis
- 中国化学工程学报（英文版） 2016年24卷第5期页码：671-676
- Affiliations：
  
  2 National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences,Beijing,China,100190
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2016.01.006
  中图分类号：
- 纸质出版：2016
- Accepted：
Scan QR Code
WeiWeng, Mingyong Wang, Xuzhong Gong, 等. Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis[J]. 中国化学工程学报（英文版）, 2016,24(5):671-676. DOI: 10.1016/j.cjche.2016.01.006.

by molten salt electrolysis[J]. Chinese Journal of Chemical Engineering, 2016, 24(5): 671-676.
WeiWeng, Mingyong Wang, Xuzhong Gong, 等. Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis[J]. 中国化学工程学报（英文版）, 2016,24(5):671-676. DOI: 10.1016/j.cjche.2016.01.006. DOI：

by molten salt electrolysis[J]. Chinese Journal of Chemical Engineering, 2016, 24(5): 671-676. DOI： 10.1016/j.cjche.2016.01.006.

摘要

Abstract

A novel and environmentally friendly route to directly prepare metallic vanadium from NaVO

by molten salt electrolysis is proposed. The feasibility about the direct electro-reduction of NaVO

to metallic vanadium is analyzed based on the thermodynamic calculations and experimental verifications. The theoretical decomposition voltage of NaVO

to metallic vanadium is only 0.47 V at 800℃ and much lower than that of the alkali and alkali earth metal chloride salts. The value is slightly higher than that of low-valence vanadium oxides such as V

and VO. However

the low-valence vanadium oxides can be further electro-reduced to metallic vanadium thermodynamically. The thermodynamic analysis is verified by the experimental results. The direct preparation of metallic vanadium from NaVO

by molten salt electrolysis is feasible.

关键词

Keywords

references

浏览量

190

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Thermodynamic feasibility of nickel and cerium oxides as versatile oxygen carriers in chemical looping reforming of methane-rich feedstocks

Syngas production from chemical looping reforming of ethanol over iron-based oxygen carriers: Theoretical analysis and experimental investigation

Investigation into Syngas Generation from Solid Fuel Using CaSO4-based Chemical Looping Gasification Process

Controllable synthesis of Ni3S2/V3S4@NF-xF(x=0, 4, 8) catalysts for efficient hydrogen production in seawater and urea electrolyte

Mechanochemical preparation and properties of B-N doped carbon materials based on calcium carbide

Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO3 by molten salt electrolysis

Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO3 by molten salt electrolysis

DOI：10.1016/j.cjche.2016.01.006

摘要

Abstract

关键词

Keywords

references

Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis

Thermodynamic analysis on the direct preparation of metallic vanadium from NaVO₃ by molten salt electrolysis