Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies

N. Sivarajasekar; R. Baskar

doi:10.1016/j.cjche.2015.08.029

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Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies

分离科学与工程 | Updated：2026-01-06

- Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies
- Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies
- 中国化学工程学报（英文版） 2015年23卷第10期页码：1610-1619
- Affiliations：
  
  Department of Chemical Engineering, Kongu Engineering College, Perundurai, Erode 638052, Tamil Nadu,India
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2015.08.029
  中图分类号：
- 纸质出版：2015
- Accepted：
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N. Sivarajasekar, R. Baskar. Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies[J]. 中国化学工程学报（英文版）, 2015,23(10):1610-1619.

seeds: Batch and fixed-bed column studies[J]. Chinese Journal of Chemical Engineering, 2015, 23(10): 1610-1619.
N. Sivarajasekar, R. Baskar. Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies[J]. 中国化学工程学报（英文版）, 2015,23(10):1610-1619. DOI： 10.1016/j.cjche.2015.08.029.

seeds: Batch and fixed-bed column studies[J]. Chinese Journal of Chemical Engineering, 2015, 23(10): 1610-1619. DOI： 10.1016/j.cjche.2015.08.029.

摘要

Abstract

Sulphuric acid activated immature Gossypium hirsutum seed (AIGHS) was prepared to biosorbe basic violet 10 (BV10) from aqueous solutions. Methylene blue number

iodine number and Brunauer-Emmett-Teller surface analysis indicated that the AIGHS were hetero-porous. Boehm titrations and Fourier-transform infrared spectra demonstrated the chemical heterogeneity of the AIGHS surface. Batch biosorption studies were used to examine the effects of process parameters in the following range: pH 2-12

temperature 293-313 K

contact time 1-5 h and initial concentration 200-600 mg·L

-1

. The matching of equilibrium data with the Langmuir-Freundlich formof isotherms indicated that the BV10 was adsorbed via chemisorption and pore diffusion. Kinetic investigation indicated multiple order chemisorption through an Avrami kinetic model. Film diffusion controlled the rate of BV10 biosorption onto AIGHS. The spontaneous and endothermic nature of sorptionwas corroborated by thermodynamic study. Continuous biosorption experimentswere performed using a fixed-bed column and the influence of operating parameters was explored for different ranges of initial concentration 100-300 mg·L

-1

bed height 5-10 cm

and flow rate 2.5-4.5 ml·min

-1

. A dose response model accurately described the fixed-bed biosorption data. An external mass transfer correlation was formulated explaining BV10-AIGHS sorption.

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