Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

Tareque Odoom-Wubah; Mingming Du; Williams Brown Osei; Daohua Sun; Jiale Huang; Qingbiao Li

doi:10.1016/j.cjche.2015.08.009

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Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

材料与产品工程 | Updated：2026-01-06

- Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation
- Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation
- 中国化学工程学报（英文版） 2015年23卷第11期页码：1907-1915
- Affiliations：
  
  1. 2 Environmental Science Research Center, College of the Environment & Ecology, Xiamen University,Xiamen,China,361005
  2. 3 College of Chemistry & Life Science, Quanzhou Normal University,Quanzhou,China,362000
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2015.08.009
  中图分类号：
- 纸质出版：2015
- Accepted：
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Tareque Odoom-Wubah, Mingming Du, Williams Brown Osei, 等. Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation[J]. 中国化学工程学报（英文版）, 2015,23(11):1907-1915.

Tareque Odoom-Wubah, Mingming Du, Williams Brown Osei, Daohua Sun, Jiale Huang, Qingbiao Li. Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation[J]. Chin.J.Chem.Eng., 2015, 23(11): 1907-1915.
Tareque Odoom-Wubah, Mingming Du, Williams Brown Osei, 等. Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation[J]. 中国化学工程学报（英文版）, 2015,23(11):1907-1915. DOI： 10.1016/j.cjche.2015.08.009.

Tareque Odoom-Wubah, Mingming Du, Williams Brown Osei, Daohua Sun, Jiale Huang, Qingbiao Li. Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation[J]. Chin.J.Chem.Eng., 2015, 23(11): 1907-1915. DOI： 10.1016/j.cjche.2015.08.009.

摘要

Abstract

Microorganism-mediated

hexadecyltrimethylammonium chloride (CTAC)-directed (MCD) method was employed in this work to synthesize Pd nanoflowers (PdNFs). Proper Pichia pastoris cells (PPCs) dosage

ascorbic acid (AA)

Pd(NO

)

and CTAC concentrations were essential for the growth of the PdNFs. The size of the assynthesized PdNFs could be tuned by adjusting the amount of Pd(NO

)

solution and dosage of PPCs used. Characterization techniques such as X-ray diffraction

transmission electron microscopy

and X-ray photoelectron spectroscopy were used to verify the nature of the PdNFs. Finally the PdNF/PPC nanocomposites were immobilized onto TiO

supports to obtain bio-PdNF/TiO

catalysts which showed excellent catalytic activity for CO oxidation

obtaining 100% conversion at 100 ℃ and remaining stable over a period of 52 h of reaction time.

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