Daohong Xia, Shengjuan Jiang, Lantao Li, 等. The biomimetic catalytic synthesis of acetal compounds using β-cyclodextrin as catalyst[J]. 中国化学工程学报(英文版), 2016,24(1):146-150.
Daohong Xia, Shengjuan Jiang, Lantao Li, Yuzhi Xiang, Lijun Zhu. The biomimetic catalytic synthesis of acetal compounds using β-cyclodextrin as catalyst[J]. Chin.J.Chem.Eng., 2016, 24(1): 146-150.
Daohong Xia, Shengjuan Jiang, Lantao Li, 等. The biomimetic catalytic synthesis of acetal compounds using β-cyclodextrin as catalyst[J]. 中国化学工程学报(英文版), 2016,24(1):146-150.DOI: 10.1016/j.cjche.2015.06.008.
Daohong Xia, Shengjuan Jiang, Lantao Li, Yuzhi Xiang, Lijun Zhu. The biomimetic catalytic synthesis of acetal compounds using β-cyclodextrin as catalyst[J]. Chin.J.Chem.Eng., 2016, 24(1): 146-150.DOI: 10.1016/j.cjche.2015.06.008.
The biomimetic catalytic synthesis of acetal compounds using β-cyclodextrin as catalyst
摘要
Abstract
Based on the principle of biomimetic catalysis
β-cyclodextrin was applied to the acetalation reaction as a facile and efficient catalyst
and the synthesis was environmentally friendly with atomic economy. The influencing factors of the acetalation reaction e.g. the reaction time
the volume of water-carrying agent
the molar ratio of catalyst to benzaldehyde and the molar ratio of glycol to benzaldehyde had been studied. The yield of benzaldehyde glycol acetal would reach amaximum of 81.3% under the conditions approached. Six of other acetals were also synthesized. Moreover
a plausible reaction mechanism for the formation of acetal had been proposed.
关键词
Keywords
references
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相关作者
Khan Afsar
Hong Ran
Chen Saisai
Liu Tingting
Kaya Savaş
Chen Weihua
Xu Dayong
Bouba Talami
相关机构
School of Chemistry and Environmental Science, Shangrao Normal University
Sivas Cumhuriyet University, Faculty of Science, Department of Chemistry
School of Chemical and Environmental Engineering, Anhui Polytechnic University
Laboratory Division, Exploration and Production Activity, Sonatrach, 1st Novembre Street
Institut de Chimie de Clermont-Ferrand, Université Clermont Auvergne, UMR 6296, BP 10448, F-63000-Ferrand