Jiawei Wang, Dehua Che, Wei Qin. Extraction of rubidium by t-BAMBP in cyclohexane[J]. 中国化学工程学报(英文版), 2015,23(7):1110-1113.
-BAMBP in cyclohexane[J]. Chinese Journal of Chemical Engineering, 2015, 23(7): 1110-1113.
Jiawei Wang, Dehua Che, Wei Qin. Extraction of rubidium by t-BAMBP in cyclohexane[J]. 中国化学工程学报(英文版), 2015,23(7):1110-1113.DOI: 10.1016/j.cjche.2015.04.005.
-BAMBP in cyclohexane[J]. Chinese Journal of Chemical Engineering, 2015, 23(7): 1110-1113.DOI: 10.1016/j.cjche.2015.04.005.
Extraction of rubidium by t-BAMBP in cyclohexane
摘要
Abstract
4-Tert-butyl-2-(α-methylbenzyl) phenol (t-BAMBP)was used in cyclohexane in the extraction of rubidiumfrom brine sources containing lithium. The effect of t-BAMBP concentration and aqueous phase pH on the rubidium and lithium extraction equilibrium was studied. t-BAMBP/cyclohexane was efficient and selective for rubidium extraction with optimal operating conditions being pH of 13.0 and initial t-BAMBP concentration of 1.0 mol·L
-1
. The stoichiometry of the complex of t-BAMBP with rubidium is 4:1. The apparent extraction equilibrium constant of rubidium was calculated by fitting the experimental data.
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