Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation

Tong Liu; Yunlong Huang; Chao Wang; Qiang Tang; Jinfu Wang

doi:10.1016/j.cjche.2014.11.003

Your Location：

Home >

Browse articles >

Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation

催化、动力学与反应工程 | Updated：2026-01-06

- Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation
- Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation
- 中国化学工程学报（英文版） 2015年23卷第1期页码：71-75
- Affiliations：
  
  Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University,Beijing,China,100084
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2014.11.003
  中图分类号：
- 纸质出版：2015
- Accepted：
Scan QR Code
Tong Liu, Yunlong Huang, Chao Wang, 等. Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation[J]. 中国化学工程学报（英文版）, 2015,23(1):71-75.

Tong Liu, Yunlong Huang, Chao Wang, Qiang Tang, Jinfu Wang . Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation[J]. Chin.J.Chem.Eng., 2015, 23(1): 71-75.
Tong Liu, Yunlong Huang, Chao Wang, 等. Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation[J]. 中国化学工程学报（英文版）, 2015,23(1):71-75. DOI： 10.1016/j.cjche.2014.11.003.

Tong Liu, Yunlong Huang, Chao Wang, Qiang Tang, Jinfu Wang . Effect of chloralkanes on the phenyltrichlorosilane synthesis by gas phase condensation[J]. Chin.J.Chem.Eng., 2015, 23(1): 71-75. DOI： 10.1016/j.cjche.2014.11.003.

摘要

Abstract

To enhance the process of phenyltrichlorosilane synthesis using gas phase condensation

a series of chloralkanes were introduced. The influence of temperature and chloralkane amount on the synthesis was studied based on the product distribution from a tubular reactor. The promoting effect of chloralkane addition was mainly caused by the chloralkane radicals generated by the dissociation of C-Cl bond. The promoting effect of the chloromethane withmore chlorine atomswas better than thosewith less chlorine atoms. Intermediates detected fromthe reactions with isoprene and bromobenzene demonstrated that both trichlorosilyl radical and dichlorosilylene existed in the reaction system in the presence of chloralkanes. A detailed reaction scheme was proposed.

关键词

Keywords

references

浏览量

110

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Study on trifluoromethanesulfonic acid-promoted synthesis of daidzein: Process optimization and reaction mechanism

Synthesis of methyl diphenylmethane dicarbamate by methyl phenylcarbamate condensation catalyzed by NKC-9: Non-phosgene preparation of key precursors for diphenylmethane diisocyanate

Dual-charged, non-swelling amine/carboxyl functionalized Fe—Mn mixed oxide composite for simultaneous removal of anionic and cationic azo dyes: Experimental and DFT studies

Efficiency and sustainability for removing organic pollutants in aqueous solution: An innovative composite material

Controllable synthesis of hydrogen-bonded organic framework encapsulated enzyme for continuous production of chiral hydroxybutyric acid in a two-stage cascade microreactor