Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

Hualing Yang; Ji Chen; WeiWang; Hongmin Cui; Dongli Zhang; Yu Liu

doi:10.1016/j.cjche.2014.09.010

Your Location：

Home >

Browse articles >

Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow

研究简报 | Updated：2026-01-06

- Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow
- Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow
- 中国化学工程学报（英文版） 2014年22卷第10期页码：1174-1177
- Affiliations：
  
  1. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun,China,130022
  2. School of Chemistry and Chemical Engineering, Nantong University,Nantong,China,226019
  3. Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, China Academy of Geological Sciences,Zhengzhou,China,450006
- Author bio：
- Funds：
- DOI：10.1016/j.cjche.2014.09.010
  中图分类号：
- 纸质出版：2014
- Accepted：
Scan QR Code
Hualing Yang, Ji Chen, WeiWang, 等. Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow[J]. 中国化学工程学报（英文版）, 2014,22(10):1174-1177.

Hualing Yang, Ji Chen, WeiWang, Hongmin Cui, Dongli Zhang, Yu Liu. Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow[J]. , 2014, 22(10): 1174-1177.
Hualing Yang, Ji Chen, WeiWang, 等. Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow[J]. 中国化学工程学报（英文版）, 2014,22(10):1174-1177. DOI： 10.1016/j.cjche.2014.09.010.

Hualing Yang, Ji Chen, WeiWang, Hongmin Cui, Dongli Zhang, Yu Liu. Extraction Kinetics of Lanthanum in Chloride Medium by Bifunctional Ionic Liquid [A336][CA-12] Using a Constant Interfacial Cellwith Laminar Flow[J]. , 2014, 22(10): 1174-1177. DOI： 10.1016/j.cjche.2014.09.010.

摘要

Abstract

The extraction kinetics of La(Ⅲ) from aqueous chloride solutions into

-heptane solutions of bifunctional ionic liquid extractant [A336

]

[CA-12

]

(tricaprylmethylammonium sec-octylphenoxy acetic acid) was investigated using a constant interfacial cell with laminar flow. The effects of stirring speed

temperature and specific interfacial area on the extraction rate were examined. The results indicate that mass transfer kinetics of La(Ⅲ) is a mixed-controlled process influenced by interfacial reaction. On the basis ofmass transfer kinetic results in the extraction of La(Ⅲ) by [A336

]

[CA-12

]

the extraction rate equation of La(Ⅲ) is proposed in terms of pseudo-firstorder constants

which is supported by the measured thermodynamic equations. The mass-transfer kinetic model deduced from the rate controlling step is adequate to interpret the experimental data qualitatively.

关键词

Keywords

references

浏览量

Downloads

CSCD

文章被引用时，请邮件提醒。

Submit

工具集

关联资源

Non-phosgene synthesis processes of isocyanates: One-step and two-step routes

CO2 leakage behavior from CO2 hydrate-liquid CO2-seawater coexistence system in unsealed sediments

Synthesis of chemiluminescent carbonized polymer dots under atmospheric conditions for multimode luminescence anti-counterfeiting

CFD-PBM simulation of liquid-liquid dispersions in an industrial pulsed disc and doughnut column with directly measured breakup and coalescence kernels

Research on the electrostatic spray characteristics of ethanol/n-butanol blended fuels