A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

汪超; 王光润; 王金福

doi:10.1016/S1004-9541(14)60034-3

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A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

催化、动力学与反应工程 | Updated：2026-01-06

- A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride
- A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride
- 中国化学工程学报（英文版） 2014年22卷第3期页码：299-3041004-954160034-3
- Affiliations：
  
  Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University,Beijing,China,100084
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(14)60034-3
  中图分类号：
- 纸质出版：2014
- Accepted：
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汪超, 王光润, 王金福. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. 中国化学工程学报（英文版）, 2014,22(3):299-3041004-954160034-3.

WANG Chao, WANG Guangrun, WANG Jinfu. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. Chin.J.Chem.Eng., 2014, 22(3): 299-304.
汪超, 王光润, 王金福. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. 中国化学工程学报（英文版）, 2014,22(3):299-3041004-954160034-3. DOI： 10.1016/S1004-9541(14)60034-3.

WANG Chao, WANG Guangrun, WANG Jinfu. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. Chin.J.Chem.Eng., 2014, 22(3): 299-304. DOI： 10.1016/S1004-9541(14)60034-3.

摘要

Abstract

A bi-component catalyst comprising CuCl and metallic copper was used in the direct synthesis of methylchlorosilane to study the catalytic synergy between the different copper sources. The catalyst exhibited high activity and high selectivity of dimethyldichlorosilane (M2) in the stirred bed reactor. The effect of the proportion of CuCl used was studied and 10%-30% CuCl gave the best yield of M2. The use of CuCl decreased the induction period of reaction

improved the selectivity in the induction stage

and gave a longer stable stage. These results suggest that bi-component catalyst has advantages in the direct synthesis reaction.

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