Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

马征; 董晓霞; 胡玉峰; 张柏松; 徐长英; 刘艳升

doi:10.1016/S1004-9541(13)60640-0

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Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

化工热力学 | Updated：2026-01-06

- Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution
- Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution
- 中国化学工程学报（英文版） 2013年21卷第12期页码：1370-13751004-954160640-0
- Affiliations：
  
  2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum,Beijing,China,102249
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(13)60640-0
  中图分类号：
- 纸质出版：2013
- Accepted：
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马征, 董晓霞, 胡玉峰, 等. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. 中国化学工程学报（英文版）, 2013,21(12):1370-13751004-954160640-0.

MA Zheng, DONG Xiaoxia, Hu Yufeng, ZHANG Bosong, XU Changying, LIU Yansheng. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chin.J.Chem.Eng., 2013, 21(12): 1370-1375.
马征, 董晓霞, 胡玉峰, 等. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. 中国化学工程学报（英文版）, 2013,21(12):1370-13751004-954160640-0. DOI： 10.1016/S1004-9541(13)60640-0.

MA Zheng, DONG Xiaoxia, Hu Yufeng, ZHANG Bosong, XU Changying, LIU Yansheng. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chin.J.Chem.Eng., 2013, 21(12): 1370-1375. DOI： 10.1016/S1004-9541(13)60640-0.

摘要

Abstract

It is important to know how ILs (ionic liquids) influence organic reaction. In this paper

activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs

such as Diels-Alder

esterification and Friedel-Crafts reaction

the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

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