龚志金, 王建莉, 吴丽梅, 等. Fabrication of Super Hydrophobic Surfaces on Copper by Solution-immersion[J]. 中国化学工程学报(英文版), 2013,21(8):920-9261004-954160569-8.
GONG Zhijin, WANG Jianli, WU Limei, WANG Xiaoyu, LÜ Guocheng, LIAO Libing. Fabrication of Super Hydrophobic Surfaces on Copper by Solution-immersion[J]. Chin.J.Chem.Eng., 2013, 21(8): 920-926.
龚志金, 王建莉, 吴丽梅, 等. Fabrication of Super Hydrophobic Surfaces on Copper by Solution-immersion[J]. 中国化学工程学报(英文版), 2013,21(8):920-9261004-954160569-8.DOI: 10.1016/S1004-9541(13)60569-8.
GONG Zhijin, WANG Jianli, WU Limei, WANG Xiaoyu, LÜ Guocheng, LIAO Libing. Fabrication of Super Hydrophobic Surfaces on Copper by Solution-immersion[J]. Chin.J.Chem.Eng., 2013, 21(8): 920-926.DOI: 10.1016/S1004-9541(13)60569-8.
Fabrication of Super Hydrophobic Surfaces on Copper by Solution-immersion
Super hydrophobic copper wafer was prepared by means of solution immersion and surface self-assembly methods. Different immersion conditions were explored for the best hydrophobic surface. Scanning electron microscopy (SEM)
X-ray diffraction (XRD)
energy dispersive spectrometer (EDS) and water contact angle measurements were used to investigate the morphologies
microstructures
chemical compositions and hydrophobicity of the produced films on copper substrates
respectively. Results show that the super hydrophobic surface is composed of micro structure of Cu
7
S
4
. The films present a high water contact angle larger than 150°
a low sliding angle less than 3°
good abrasion resistance and storage stability. The molecular dynamics simulation confirms that N-dodecyl mercaptan molecules link up with Cu
7
S
4
admirably
compared with Cu
which contributes to the stable super hydrophobic surface.
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Keywords
references
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相关作者
Sun Nana
Dong Hongmei
Liu Jian
Hu Jianbo
Rias Becik Sinawang
Duan Lian
Yuan Wenjun
Liu Dongjie
相关机构
School of Pipeline Engineering, Xi'an Shiyou University
State Key Laboratory of Fluorine & Nitrogen Chemicals, School of Chemical Engineering and Technology, Xi'an Jiaotong University
Hubei Key Laboratory for Novel Reactor and Green Chemistry Technology, WIT-Qianjiang Research Institute of Green Chemical Industry, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology
College of Chemistry and Chemical Engineering, Taiyuan University of Technology
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences