Na-A zeolite was synthesized using oil shale ash (OSA)

which is a solid by-product of oil shale processing. The samples were characterized by various techniques

such as scanning electron microscopy

X-ray diffraction and Brunauer Emmet Teller method. The batch isothermal equilibrium adsorption experiments were performed to evaluate the ability of Na-A zeolite for removal of Cu(II) from aqueous solutions. The effects of operating parameters

such as concentration of copper solutions

adsorbent dosages

pH value of solutions and temperature

on the adsorption efficiency were investigated. The equilibrium adsorption data were fitted with Langmuir and Freundlich models. The maximum adsorption capacity of Na-A zeolite obtained from the Langmuir adsorption isotherm is 156.7 mg·g

-1

of Cu(II). The increase of pH level in the adsorption process suggests that the uptake of heavy metals on the zeolite follows an ion exchange mechanism. The batch kinetic data fit the pseudo-second order equation well. The thermodynamic parameters

such as changes in Gibbs free energy (DG)

enthalpy (DH) and entropy (DS)

are used to predict the nature of the adsorption process. The negative DG values at different temperatures confirm that the adsorption processes are sp

ontaneous.