杨磊, 王胜强, 王瑞聪, 等. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. 中国化学工程学报(英文版), 2013,21(5):558-5631004-954160512-1.
YANG Lei, WANG Shengqiang, WANG Ruicong, YU Hongbing. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. Chin.J.Chem.Eng., 2013, 21(5): 558-563.
杨磊, 王胜强, 王瑞聪, 等. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. 中国化学工程学报(英文版), 2013,21(5):558-5631004-954160512-1.DOI: 10.1016/S1004-9541(13)60512-1.
YANG Lei, WANG Shengqiang, WANG Ruicong, YU Hongbing. Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent[J]. Chin.J.Chem.Eng., 2013, 21(5): 558-563.DOI: 10.1016/S1004-9541(13)60512-1.
Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent
This paper presents a new selective adsorbent to remove nitrogen-containing heterocyclic compounds from model and commercial transportation diesel fuels based on characteristic reaction designed to occur in the pores of substrate. This reactive adsorbent is composed of formaldehyde
phosphotungstic acid and Santa Barbara USA (SBA)-15. The experiment was based on assumed hydroxymethylation reaction of nitrogen-containing heterocyclic compounds with formaldehyde using phosphotungstic acid as catalyst in batch and fixed-bed systems. The nitrogen concentration in the model fuel was 237.33 ng·μl
-1
carbazole and toluene were used as model nitrogen-containing heterocyclic compound and solvent
respectively. The effectiveness of reactive adsorbent for removal of nitrogen-containing heterocyclic compounds from commercial 0
#
diesel fuel containing 224.86 ng·μl
-1
nitrogen was examined in a fixed-bed reactor at 70 ℃. The results showed that nitrogen in the model fuel was very low and the nitrogen concentration in the commercial diesel reduced to 2.44 ng·μl
-1
. The demand for transportation fuel with ultra-low nitrogen is satisfied.
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相关作者
Guo Yan
Hou Tuanyuan
Wang Yongjin
Chang Liping
Wang Jiancheng
Liao Junjie
Wu Yu-Hua
Wang Jue
相关机构
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Xinjiang Normal University
Key Laboratory of Coal Science and Technology, Ministry of Education, Taiyuan University of Technology
College of Chemistry and Chemical Engineering, Taiyuan University of Technology
State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University