2 The Institute of Materials for Electrical and Electronic Engineering, University Karlsruhe, and Karlsruhe Institute of Technology,Karlsruhe,Germany,76131
黄肖微, Alexander Kromp. Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane: A Modelling Study[J]. 中国化学工程学报(英文版), 2013,21(3):324-3311004-954160485-5.
HUANG Xiaowei, Alexander Kromp. Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane: A Modelling Study[J]. Chin.J.Chem.Eng., 2013, 21(3): 324-331.
黄肖微, Alexander Kromp. Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane: A Modelling Study[J]. 中国化学工程学报(英文版), 2013,21(3):324-3311004-954160485-5.DOI: 10.1016/S1004-9541(13)60485-5.
HUANG Xiaowei, Alexander Kromp. Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane: A Modelling Study[J]. Chin.J.Chem.Eng., 2013, 21(3): 324-331.DOI: 10.1016/S1004-9541(13)60485-5.
Cooling of a Diesel Reformate Fuelled Solid Oxide Fuel Cell by Internal Reforming of Methane: A Modelling Study
In this paper a system combining a diesel reformer using catalytic partial oxidation (CPOX) with the Solid Oxide Fuel Cell (SOFC) for Auxiliary Power Unit (APU) applications is modeled with respect to the cooling effect provided by internal reforming of methane in anode gas channel. A model mixture consisting of 80% n-hexadecane and 20% 1-methylnaphthalin is used to simulate the commercial diesel. The modelling consists of several steps. First
equilibrium gas composition at the exit of CPOX reformer is modelled in terms oxygen to carbon (O/C) ratio
fuel utilization ratio and anode gas recirculation. Second
product composition
especially methane content
is determined for the methanation process at the operating temperatures ranging from 500 ℃ to 520 ℃. Finally
the cooling power provided by internal reforming of methane in SOFC fuel channel is calculated for two concepts to increase the methane content of the diesel reformate. The results show that the first concept
operating the diesel reformer at low O/C ratio and/or recirculation ratio
is not realizable due to high probability of coke formation
whereas the second concept
combining a methanation process with CPOX
can provide a significant cooling effect in addition to the conventional cooling concept which needs higher levels of excess air.
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