Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion

马庆兰; 黄强; 陈光进; 王秀林; 孙长宇; 杨兰英

doi:10.1016/S1004-9541(13)60466-8

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Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion

化工热力学 | Updated：2026-01-06

- Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion
- Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion
- 中国化学工程学报（英文版） 2013年21卷第3期页码：295-3001004-954160466-8
- Affiliations：
  
  High Pressure Fluid Phase Behavior & Property Research Laboratory, China University of Petroleum,Beijing,China,102249
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(13)60466-8
  中图分类号：
- 纸质出版：2013
- Accepted：
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马庆兰, 黄强, 陈光进, 等. Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion[J]. 中国化学工程学报（英文版）, 2013,21(3):295-3001004-954160466-8.

MA Qinglan, HUANG Qiang, CHEN Guangjin, WANG Xiulin, SUN Changyu, YANG Lanying. Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion[J]. Chin.J.Chem.Eng., 2013, 21(3): 295-300.
马庆兰, 黄强, 陈光进, 等. Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion[J]. 中国化学工程学报（英文版）, 2013,21(3):295-3001004-954160466-8. DOI： 10.1016/S1004-9541(13)60466-8.

MA Qinglan, HUANG Qiang, CHEN Guangjin, WANG Xiulin, SUN Changyu, YANG Lanying. Kinetic and Phase Behaviors of Catalytic Cracking Dry Gas Hydrate in Water-in-Oil Emulsion[J]. Chin.J.Chem.Eng., 2013, 21(3): 295-300. DOI： 10.1016/S1004-9541(13)60466-8.

摘要

Abstract

The systematic experimental studies were performed on the hydrate formation kinetics and gas-hydrate equilibrium for a simulated catalytic cracking gas in the water-in-oil emulsion. The effect of temperature

pressure and initial gas-liquid ratio on the hydrate formation was studied

respectively. The data were obtained at pressures ranging from 3.5 to 5 MPa and temperatures from 274.15 to 277.15 K. The results showed that hydrogen and methane can be separated from the C

fraction by forming hydrate at around 273.15 K which is much higher temperature than that of the cryogenic separation method

and the hydrate formation rate can be enhanced in the water-in-oil emulsion compared to pure water. The experiments provided the basic data for designing the industrial process

and setting the suitable operational conditions. The measured data of gas-hydrate equilibria were compared with the predictions by using the Chen-Guo hydrate thermodynamic model.

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