Oxidation of <i>p/o</i>-Cresols to <i>p/o</i>-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen

佘远斌; 王维洁; 李国君

doi:10.1016/S1004-9541(12)60387-5

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Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen

CATALYSIS, KINETICS AND REACTION ENGINEERING | Updated：2026-01-06

- Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen
- Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen
- 中国化学工程学报（英文版） 2012年20卷第2期页码：262-266
- Affiliations：
  
  Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology,Beijing,China,100124
- Author bio：
- Funds：
  
  Supported by the Key Project of National Natural Science Foundation of China (21036009, 20776003);the Key Project of Natural Science Foundation of Beijing (2061001);the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of the Beijing Municipality (PHR 200907105, PHR 201107104)
- DOI：10.1016/S1004-9541(12)60387-5
  中图分类号：
- 纸质出版：2012
- Accepted：
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佘远斌, 王维洁, 李国君. Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen[J]. 中国化学工程学报（英文版）, 2012,20(2):262-266. DOI: 10.1016/S1004-9541(12)60387-5.

-Cresols to
佘远斌, 王维洁, 李国君. Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen[J]. 中国化学工程学报（英文版）, 2012,20(2):262-266. DOI: 10.1016/S1004-9541(12)60387-5. DOI：

-Cresols to DOI： 10.1016/S1004-9541(12)60387-5.

摘要

Abstract

The two novel green oxidation processes of

p/o

-cresols to

p/o

-hydroxybenzaldehydes catalyzed by metalloporphyrins in the presence of molecular oxygen were developed in this work.Among the metalloporphyrins with different central ions and substituents studied

-NO

)PPCoCl and T(

-OCH

)PPFeCl presented the highest activities for

-cresol and

-cresol oxidation reactions respectively.The molar ratio of sodium hydroxide to cresols and different reaction parameters including reaction temperature

reaction time and reaction pressure have been investigated

and 69.8%/50.4% conversions of

p/o

-cresol and 86.6%/26.6% selectivities for

p/o

-hydroxybenzaldehydes were reached under optimized conditions.

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Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen

Oxidation of p/o-Cresols to p/o-Hydroxybenzaldehydes Catalyzed by Metalloporphyrins with Molecular Oxygen

DOI：10.1016/S1004-9541(12)60387-5

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Abstract

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Keywords

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