In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process
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In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process
In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process
中国化学工程学报(英文版)2012年20卷第1期 页码:158-166
Affiliations:
State Key Laboratory of Heavy Oil Processing, China University of Petroleum,Beijing,China,102249
Author bio:
Funds:
Supported by the Ministry of Science and Technology of China Through the National Basic Research Program (2010CB226905);the National Natural Science Foundation of China for the Youth (20706059)
刘海燕, 曹丽媛, 魏宝莹, 等. In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process[J]. 中国化学工程学报(英文版), 2012,20(1):158-166. DOI: 10.1016/S1004-9541(12)60376-0.
Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process[J]. Chinese Journal of Chemical Engineering, 2012, 20(1): 158-166.
刘海燕, 曹丽媛, 魏宝莹, 等. In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process[J]. 中国化学工程学报(英文版), 2012,20(1):158-166. DOI: 10.1016/S1004-9541(12)60376-0.DOI:
Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process[J]. Chinese Journal of Chemical Engineering, 2012, 20(1): 158-166.DOI: 10.1016/S1004-9541(12)60376-0.
In-situ Synthesis and Catalytic Properties of ZSM-5/Rectorite Composites as Propylene Boosting Additive in Fluid Catalytic Cracking Process
Using rectorite extrudates from calcined rectorite powder as the starting material
a series of ZSM-5/rectorite composites were prepared via the
in-situ
crystallization method.The physicochemical properties and propylene boosting performance of the resulting samples were characterized by using X-ray diffraction
and Fourier transformed in-frared spectroscopy of pyridine adsorption
respectively
and assessed by using Daqing atmospheric residue as feed-stock.The results showed that the ZSM-5/rectorite composites in which the ZSM-5 phase grows in-situ as a 2-3 μm thick layer on rectorite particles have a trimodal microporous-mesoporous-macroporous structure and thus exhibit outstanding propylene boosting performance.Compared with a commercial ZSM-5 incorporated fluid catalytic cracking catalyst
the ZSM-5/rectorite composite incorporated catalyst increased the yield and selectivity of pro-pylene by 2.44% and 5.35%
respectively.
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王淑彦
陆慧林
高金森
徐春明
孙丹
相关机构
School of Energy Science and Engineering, Harbin Institute of Technology