Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane

伍艳辉; 谭惠芬; 李佟茗; 金源

doi:10.1016/S1004-9541(11)60227-9

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Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane

Updated：2026-01-06

- Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane
- Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane
- 中国化学工程学报（英文版） 2012年20卷第4期页码：625-632
- Affiliations：
  
  Department of Chemistry, Tongji University,Shanghai,China,200092
- Author bio：
- Funds：
  
  Supported by Shanghai Natural Science Foundation (10ZR1432000);Kwang-Hua Fund for College of Civil Engineering,Tongji University
- DOI：10.1016/S1004-9541(11)60227-9
  中图分类号：
- 纸质出版：2012
- Accepted：
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伍艳辉, 谭惠芬, 李佟茗, 等. Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane[J]. 中国化学工程学报（英文版）, 2012,20(4):625-632.

WU Yanhui, TAN Huifen, LI Dongming, JIN Yuan. Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane[J]. Chin.J.Chem.Eng., 2012, 20(4): 625-632.
伍艳辉, 谭惠芬, 李佟茗, 等. Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane[J]. 中国化学工程学报（英文版）, 2012,20(4):625-632. DOI： 10.1016/S1004-9541(11)60227-9.

WU Yanhui, TAN Huifen, LI Dongming, JIN Yuan. Pervaporation of Aqueous Solution of Acetaldehyde Through ZSM-5 Filled PDMS Composite Membrane[J]. Chin.J.Chem.Eng., 2012, 20(4): 625-632. DOI： 10.1016/S1004-9541(11)60227-9.

摘要

Abstract

Hydrophobic ZSM-5 zeolite filled polydimethylsiloxane(PDMS) composite membranes with Nylon micro-filtration membrane as the support layer were prepared to separate acetaldehyde from its aqueous solution.The composite membranes were characterized by Fourier transform infrared spectroscopy and X-ray diffraction.Their structural morphology and thermal stability were also examined.The swelling study showed that the composite membranes presented higher degree of swelling in aqueous solution of acetaldehyde than in pure water at 25℃

suggesting that the membranes have stronger sorption capacity in acetaldehyde solution.The effects of ZSM-5 filling content and acetaldehyde concentration on pervaporation performance of composite membranes were investigated.The permeation experiments at different temperatures showed that both selectivity and permeation flux of composite membranes increased with temperature.With 5%ZSM-5-PDMS/Nylon membrane at acetaldehyde mass concentration of 8% and 25℃

the separation factor of acetaldehyde/water achieved 35 and the permeation flux was 233.3 g·m

-2

·h

-1

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