W. H. Cheung, S. S. Y. Lau, S. Y. Leung, 等. Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding[J]. 中国化学工程学报(英文版), 2012,20(3):515-523.
W. H. Cheung, S. S. Y. Lau, S. Y. Leung, A. W. M. Ip, G. McKay. Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding[J]. , 2012, 20(3): 515-523.
W. H. Cheung, S. S. Y. Lau, S. Y. Leung, 等. Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding[J]. 中国化学工程学报(英文版), 2012,20(3):515-523.DOI: 10.1016/S1004-9541(11)60213-9.
W. H. Cheung, S. S. Y. Lau, S. Y. Leung, A. W. M. Ip, G. McKay. Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding[J]. , 2012, 20(3): 515-523.DOI: 10.1016/S1004-9541(11)60213-9.
Characteristics of Chemical Modified Activated Carbons from Bamboo Scaffolding
bamboo scaffolding was used to produce activated carbon by carbonization at 600℃ and 900℃ with the purge of nitrogen.The 600℃ char was then further modified chemically by acids and alkalis by reflux for 6 hours.The produced chars were then characterized by nitrogen adsorption isotherm
He pyncometry
pH
elemental analysis and Boehm titration.For most of the chemically modified carbons
the micropore surface areas and volumes have increased compared with the 600℃ char
while the mesopore surface areas and volumes slightly decreased
which may have been due to the dissolving of some of the permeated inorganic matter and oxidizing deposited carbon that blocks the pore openings.For the acidic modified carbons
larger amounts of acidic groups were present in the carbons after being activated by phosphoric acid
phosphoric acid further treated with 2 mol·L
-1
nitric acid
and calcium hydroxide.Although carbon treated with 2 mol·L
-1
and 5 mol·L
-1
nitric acid also produced high acidity
the surface areas and pore volumes were relatively low
due to the destruction of pores by nitric acid oxidation.The reduction of porosity may impair the adsorption capacity.
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相关作者
L. S. Chan
W. H. Cheung
S. J. Allen
Atakan Toprak
Turkan Kopac
Xiao Liang
Xu Jiahui
Dai Jiawei
相关机构
School of Chemistry and Chemical Engineering, Queen's University Belfast,,Northern , UK
Department of Chemistry, Zonguldak Karaelmas University
Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts, College of Chemical Engineering, Zhejiang University of Technology
Xiangjiang Laboratory
School of Materials Science and Engineering, Jiangsu University of Science and Technology