Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

叶建初; 黄佳丽; 林晗丹; 曹克腾; 沙勇

doi:10.1016/S1004-9541(11)60060-8

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Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

Updated：2026-01-06

- Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst
- Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst
- 中国化学工程学报（英文版） 2011年19卷第5期页码：808-814
- Affiliations：
  
  College of Chemistry and Chemical Engineering, Xiamen University,Fujian,Xiamen,China,361005
- Author bio：
- Funds：
- DOI：10.1016/S1004-9541(11)60060-8
  中图分类号：
- 纸质出版：2011
- Accepted：
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叶建初, 黄佳丽, 林晗丹, 等. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. 中国化学工程学报（英文版）, 2011,19(5):808-814.

YE Jianchu, HUANG Jiali, LIN Handan, CAO Keteng, SHA Yong. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. , 2011, 19(5): 808-814.
叶建初, 黄佳丽, 林晗丹, 等. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. 中国化学工程学报（英文版）, 2011,19(5):808-814. DOI： 10.1016/S1004-9541(11)60060-8.

YE Jianchu, HUANG Jiali, LIN Handan, CAO Keteng, SHA Yong. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. , 2011, 19(5): 808-814. DOI： 10.1016/S1004-9541(11)60060-8.

摘要

Abstract

Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5

the kinetic-thermodynamic analysis of this reactive distillation has been carried out to get the characteristics of the reactive distillation. Results from kinetic and thermodynamic analysis indicate that the optimal pressure of this reactive distillation process should be set to higher pressure such as 0.3 or 0.4 MPa. To avoid the recovery of cyclohexanol at the top of the column

an unreactive section should be allo-cated at the upper column. In addition

the inert component benzene is more unfavorable to the reactive distillation process in comparison with the inert cyclohexane.

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